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Properties of Fe/SiO2 Core-shell Composite Particles with Different Nanoshell Thickness
SiO2纳米壳的厚度对羰基铁/SiO2核壳复合粒子的性能影响

Keywords: core-shell particles,carbonyl iron,silica,microwave absorbing
核壳结构
,羰基铁,二氧化硅,微波吸收

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Abstract:

Using a sol-gel route with polyvinyl pyrrolidone as the surfactant,the carbonyl iron microparticles were uniformly and fleetly coated by SiO_2 nanoshell,whose thickness was conve- niently different by changing reaction time.The influences of shell thickness on the properties of the Fe/SiO_2 core-shell particles were studied.The results show that increasing the thickness of SiO_2 nanoshell(D_(shell)),the anti-oxidation property of the Fe/SiO_2 core-shell composite parti- cles is obviously improved while microwave permittivity decreased monotoneously.The saturation magnetization shows a maximum value while both the coercivity and remnant magnetization show minimum values at D_(shell)=15nm.Meanwhile,the radar absorbing coating based on the Fe/SiO_2 core-shell composite particles with D_(shell)=15nm shows a maximum bandwidth of more than 10GHz, in which the reflective loss is less than-8dB.

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