Theoretical study of the Rydberg series energy levels of ns2S1/2,np2P1/2,3/2, nd2D3/2,5/2 and nf2F5/2,7/2 for a
碱金属Li,Na,K,Rb,Cs,Fr的ns2S1/2,np2P1/2,3/2, nd2D3/2,5/2 和nf2F5/2,7/2 里德伯能级理论研究

In the frame work of multi-channel quantum defect theory,the energy levels of Rydberg series of ss2S1/2,np2P1/2,np2P3/2, nd2D3/2,nd2D5/2,nf2F5/2 and nf2F7/2 of alkali-metal atom are calculated by the relativistic multi-channel theory,in five different approximations,i.e.,frozen core approximation,with consideration of Al =—1 dipole polarization effect,Al = +1 dipole polarization effect,Al =±1 dipole polarization effect,stretch effect,and both dipole polarization effects and stretch effect,respectively. The present calculations show that electron correlation effect plays an important role in the energy level of Rydberg series. In summary,dipole polarization effect is more important than the stretch effect,and the Al = +1 dipole polarization effect is more important than Al =—1 dipole polarization effect.However,stretch effect is more important for energy levels of both Rydberg series ns2S1/2,(nd2D3/2,nd2D5/2) of Na,and Rydberg series(np2P1/2,np2P3/2) of Li.