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物理学报  2004 

The synthesis and thermoelectric properties of double-atom-filled BamCenFeCo3Sb12 compounds
Ba和Ce两种原子复合填充BamCenFeCo3Sb12化合物的合成及热电性能

Keywords: skutterudite,double atoms filled,electrical conductivity,lattice thermal conductivity
方钴矿,
,双原子填充,,电导率,,晶格热导率

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Abstract:

The single_phase double_atom_filled p_type Ba m Ce n FeCo 3Sb 12 compounds were synthesized using the solid_state reaction method and also the melt reaction method. Thermoelectric properties of the p_type Ba m Ce n FeCo 3Sb 12 compound were investigated, and the results indicated that the electrical conductivity of the p_type Ba m Ce n FeCo 3Sb 12 is intervenient between the electrical conductivities of single_atom_filled compounds Ba m FeCo 3Sb 12 and Ce n FeCo 3Sb 12 .It decreased with increasing Ba and Ce filling fraction. With the same filling fraction, the lattice thermal conductivity of Ba m Ce n FeCo 3Sb 12 is found to be smaller than that of Ba m FeCo 3Sb 12 and Ce n FeCo 3Sb 12 .

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