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物理学报  2005 

The magnetic fine structure calculation of helium 10G-10M Rydberg states
氦原子Rydberg态10G—10M磁精细结构的计算

Keywords: helium atom,Rydberg state,magnetic fine structure,self-consistent iteration
氦原子,
,Rydberg态,磁精细结构,自洽迭代

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Abstract:

With self-consistent iterative method for solving the Hartree equation, precise numerical wavefunctions of helium lsnl configuration are generated to build up the LS term wavefunctions as basis sets. The magnetic fine structure of helium 10G-10M Rydberg states is calculated with the linear variation method, including both the exchange and magnetic interaction under the Breit-Bethe approximation. The calculated results agree well with the existing experiment data. Some ideas and discussions for further improvement are given.

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