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物理学报  2002 

Pressure difference between inside and outside of a drop and its critical radius in dropwise condensation
滴状冷凝中液滴的内外压差及临界半径

Keywords: dropwise condensation,liquid drop,pressure difference,critical radius
滴状冷凝
,液滴,压差,临界半径

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Abstract:

It was proved using the thermodynamic method that the pressure difference between the inside and outside of a liquid drop sitting on a solid surface follows the classical Laplace equation, and this was further validated using the mechanics method. Such a pressure difference depends only on the surface tension of the liquid and the radius of the drop but is independent of the liquid solid contact angle.Similarly, the critical radius of a drop in dropwise condensation is also independent of the contact angle and can be calculated using the classical Kalvin equation.

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