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物理学报 1983
THE STATISTICAL THEORY OF CHEMICAL REACTIONS
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Abstract:
In this article, a quantum statistical theory of fluctuation in chemical reaction systems has been developed. Starting from the Liouville equation, the equation for characteristic function and distribution function of density fluctuation has been obtained by projection operator method. The results confirm our previous phenomeno-logical theory. Finally, the correction terms of statistical theory and its influences on spectrum of fluctuation waves has been discussed.