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Frontiers in Science 2012
Comparative Study of Indion-AGR and Duolite A-638 Anion Exchange Resins by Application of 131I and 82 Br as a Tracer IsotopesKeywords: Indion-AGR, Duolite A-638, Tracer Applications, Reaction Kinetics, Ion-Isotopic Exchange Reactions, 131I, 82Br, Distribution Coefficient, Reaction Rate Abstract: The present study deals with modeling of ion-isotopic exchange reaction kinetics by application of radioactive tracer isotopes 82Br and 131I. The bromide and iodide ion-isotopic exchange reactions was carried out by using weak base anion exchange resins Indion-AGR and Duolite A-638. It was observed that for both the resins, reaction rate decreases with rise in temperature and increases with increase in ionic concentration. The study was extended further for characterization of these resins based on their performance under different operational parameters. It was observed that the percentage/amount of ions exchanged and distribution coefficient values calculated for Duolite A-638 was higher than Indion-AGR resins under identical operational parameters, indicating superior performance of Duolite A-638 over Indion-AGR resins.
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