EFECTO DEL SUSTITUYENTE SOBRE EL ANILLO PORFIRíNICO Y EL AGENTE OXIDANTE EN LA FUNCIONALIZACIóN DE COMPUESTOS ALIFáTICOS

in this work was studied the functionalizations of squalane and tetradecane varying the electronic nature of the substituents over the porphyrinic ring and the oxidizing agent (kio4,2khso5-khs(vk2so4, naclo and h2o2). three metallo-porphyrins (mn(ttp)cl, mn ρ-no2tpp) cl and mn(trimeotpp)cl) were synthesized and characterized with yields of 40, 52 and 43% respectively. twenty four different functionalisation systems were carried out and quantified by gas chromatography using internal standard method and the products were identified by gas chromatography-mass spectroscopy. the functionalisations were quantified by cg and the products identified by gc-ms and ft-ir. the results showed that a good choice porphyirin-oxidizing agent pair can produce functionalization yields up to 42% for tetradecane and 80% for squalane.