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Photo-Physical Properties of Stilbine-3 (STB-3) Laser Dyes Embedded in Sol-Gel Glasses

DOI: 10.4236/njgc.2016.64008, PP. 64-74

Keywords: Sol-Gel Glass, Laser Dye , Stilbine-3 (STB-3)

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Solid-state tunable dye laser materials developed by incorporation of stable laser dye molecules into solid host matrices like polymers, organically modified silicates (ORMOSILS) and porous sol-gel glasses. These materials have technical advantages such as compactness, better manageability and suitability for field measurement. The recent research work with highly porous sol-gel glasses having good transparency in UV-Near UV region used as solid host for solid-state dye laser materials has attracted a great deal of attention because of its high potential utility than polymers. Two different procedure’s are used for incorpoerating the Stilbine-3 (STB-3) laser dyes into porous sol-gel matrices such as dope or dip methods. In dope method dye is mixed at the sol state and drying is carried out afterward; while in dip method matrix is first prepared and the matrix is dipped in desired dye solution. After preparation of these dye embedded sol-gel glasses we studied their spectroscopic properties of using absorption and fluorescence spectroscopy. Along with spectroscopy properties, the studies for longevity or the shelf life and lasing action of these materials were carried out. Laser dye STB-3 incorporated in sol-gel glass samples shows the same result as in methanolic solution.


[1]  Schafer, F.P. (1990) Dye Lasers. Springer Verlag, Berlin.
[2]  Duarte, F.J. and Hillman, L.W. (1990) Dye Laser Principles. Academic, New York.
[3]  Deshpande, A.V. and Mhatre, V.B. (1996) Correlation of Lasing and Fluorescence Properties of Bromine Containing Fluorescein Derivatives. Journal of Luminescence, 65, 313-319.

[4]  Reynolds, G.A. and Drexhage, K.H. (1975) New Coumarin Dyes with Rigidized Structure for Flashlamp-Pumped Dye Lasers. Optics Communications, 13, 222-225.

[5]  Ramalingam, A. and Vijila, C. (1999) A Study of Spectral and Gain Characteristics of Substituted Amino Coumarins under Nitrogen Laser Excitation. Journal of Molecular Liquids, 81, 237-244.

[6]  Giffin, S.M., McKinnie, I.T., Wadsworth, W.J., Woolhouse, A.D., Smith, G.J. and Haskell, T.G. (1999) Solid State Dye Lasers Based on 2-Hydroxyethyl Methacrylate and Methyl Methacrylate Co-Polymers. Optics Communications, 161, 163-170.

[7]  Hermes, R.E., Allik, T.H., Chandra, S. and Hutchinson, J.A. (1993) High Efficiency Pyrromethene Doped Solid State Dye Lasers. Applied Physics Letters, 63, 877-879.

[8]  Altman, J.C., Stone, R.E., Dunn, B. and Nishida, F. (1991) Solid-State Laser Using a Rhodamine-Doped Silica Gel Compound. IEEE Photonics Technology Letters, 3, 189-190.

[9]  Canva, M., Georges, P., Perelgritz, J.F., Brun, A., Chaput, F. and Boilot, J.P. (1995) Perylene- and Pyrromethene-Doped Xerogel for a Pulsed Laser. Applied Optics, 34, 428-432.

[10]  Maslyukov, A., Sokolov, S., Kaivola, M., Nyholm, K. and Popov, S. (1995) Solid-State Dye Laser with Modified Poly(methyl methacrylate)-Doped Active Elements. Applied Optics, 34, 1516-1518.

[11]  Costela, A., Florido, F., Gercia-Moreno, I., Duchowicz, R., Amat-Guerri, F., Figuera, J.M. and Sastre, R. (1995) Solid-State Dye Lasers Based on Copolymers of 2-Hydroxyethyl Methacrylate and Methyl Methacrylate Doped with Rhodamine 6G. Applied Physics B, 60, 383-389.

[12]  Costela, A., Gercia-Moreno, I., Figuera, J.M., Amat-Guerri, F. and Sastre, R. (1996) Solid State Dye Lasers Based on Polymers Incorporating Covalently Bonded Modified Rhodamine 6G. Applied Physics Letters, 68, 593-595.

[13]  Ye, C., Lam, K.S., Chik, K.P., Lo, D. and Wang, K.H. (1996) Output Performance of a Dye Doped Sol Gel Silica Laser in the Near UV. Applied Physics Letters, 69, 3800-3802.

[14]  Hu, W., Ye, H., Li, C., Jiang, Z. and Zhou, F. (1997) All-Solid-State Tunable DCM Dye Laser Pumped by a Diode-Pumped Nd:YAG Laser. Applied Optics, 36, 579-583.

[15]  Chandra, S., Allik, T.A., Hutchinson, J.A., Fox, J. and Swin, C. (1997) Tunable Ultraviolet Laser Source Based on Solid-State Dye Laser Technology and CsLiB6O10 Harmonic Generation. Optics Letters, 22, 209-211.

[16]  Duarte, F.J., Costela, A., Gercia-Moreno, I., Sastre, R., Ehrlich, J.J. and Tylor, T.S. (1997) Dispersive Solid-State Dye Laser Oscillators. Optical and Quantum Electronics, 29, 461- 472.

[17]  Rahn, M.D., King, T.A. and Hamblett, A.I. (1997) Photostability Enhancement of Pyrromethene 567 and Perylene Orange in Oxygen-Free Liquid and Solid Dye Lasers. Applied Optics, 36, 5862-5871.

[18]  Faloss, M., Canva, M., Georges, P., Brun, A., Chaput, F. and Boilot, J.P. (1997) Toward Millions of Laser Pulses with Pyrromethene- and Perylene-Doped Xerogel. Applied Optics, 36, 6760-6763.

[19]  Knobbe, E.T., Dunn, B., Fuqua, P.D. and Nishida, F. (1990) Laser Behavior and Photostability Characteristics of Organic Dye Doped Silicate Gel Materials. Applied Optics, 29, 2729-2733.
[20]  McKiernan, J.M., Yamanaka, S.A. Dunn, B. and Zink, J.I. (1990) Spectroscopy and Laser Action of Rhodamine 6G Doped Aluminosilicate Xerogels. The Journal of Physical Chemistry, 94, 5652-5654.

[21]  Lo, D., Parris, J.E. and Lawless, J.L. (1992) Multi-Megawatt Superradiant Emissions from Coumarin-Doped Sol-Gel Derived Silica. Applied Physics B, 55, 365-367.

[22]  Lo, D., Parris, J.E. and Lawless, J.L. (1993) Laser and Fluorescence Properties of Dye-Doped Sol-Gel Silica from 400 nm to 800 nm. Applied Physics B, 56, 385-390.

[23]  Bauer, R.K., Balter, A., Kowalczyk, A. and Jung, C. (1980) Some Luminescence Properties of the Laser Dye Stilbene 3. Zeitschrift fur Naturforschung A, 35, 1319-1324.

[24]  Fukuda, M. and Mito, K. (2000) Laser Oscillation of Energy Transfer Solid-State Dye Laser with a Thin-Film Ring Resonator. Japanese Journal of Applied Physics, 39, 3470-3471.

[25]  Weissbeck, A., Langhoff, H. and Beck, A. (1995) Lasing and Fluorescence Properties of Dye-Doped Xerogel. Applied Physics B, 61, 253-255.

[26]  Lam, K.S. and Lo, D. (1998) Lasing Behavior of Sol-Gel Silica Doped with UV Laser Dyes. Applied Physics B, 66, 427-430.

[27]  Ye, C., Lam, K.S., Lam, S.K. and Lo, D. (1997) Dye-Doped Sol-Gel Derived Silica Laser Tunable from 352 nm to 387 nm. Applied Physics B, 65, 109-111.

[28]  Lam, S.K., Zhu, X.L. and Lo, D. (1999) Single Longitudinal Mode Lasing of Coumarin-Doped Sol-Gel Silica Laser. Applied Physics B, 68, 1151-1153.

[29]  Arbeloa, T.L., Arbeloa, F.L., Tapia, M.J. and Arbeloa, I.L. (1993) Hydrogen-Bonding Effect on the Photophysical Properties of 7-Aminocoumarin Derivatives. Journal of Physical Chemistry, 97, 4704-4707.

[30]  Jones, G., Jackson, W.R. and Halpern Chem, A.M. (1980) Medium Effects on Fluorescence Quantum Yields And Lifetimes for Coumarin Laser Dyes. Physics Letters, 72, 391-395.

[31]  Jones, G., Jackson, W.R., Yoo Choi, C. and Bergmark, W.R. (1985) Solvent Effects on Emission Yield and Lifetime for Coumarin Laser Dyes. Requirements for a Rotatory Decay Mechanism. Journal of Physical Chemistry, 89, 294-300.

[32]  Gustavsson, T., Cassara, L., Gulbinas, V., Mialocq, J.C., Pommeret, S., Sorgius, M. and van der Meulen, P. (1998) Femtosecond Spectroscopic Study of Relaxation Processes of Three Amino-Substituted Coumar in Dyes in Methanol and Dimethyl Sulfoxide. Journal of Physical Chemistry A, 102, 4229-4245.

[33]  Kunjappu, J.T. (1993) Photophysical Properties of Five Laser Dyes (C120, Cl, C102, C1F and C153) in Homogeneous, Surfactant and Membrane Media. Journal of Photochemistry and Photobiology A: Chemistry, 71, 269-273.

[34]  Costela, A., Gercia-Moreno, I., Barosso, J. and Sastre, R. (1998) Studies on Laser Action from Polymeric Matrices Doped with Coumarin 503. Applied Physics B, 67, 167-173.

[35]  Suratwala, T., Gardlund, Z., Davidson, K., Uhlmann, D.R., Watson, J., Bonilla, S. and Peyghambarian, N. (1998) Silylated Coumarin Dyes in Sol-Gel Hosts. 2. Photostability and Sol-Gel Processing. Chemistry of Materials, 10, 199-209.

[36]  Deshpande, A.V. and Namdas, E.B. (2000) Correlation between Lasing and Photophysical Performance of Dyes in Polymethylmethacrylate. Journal of Luminescence, 91, 25-31.

[37]  Costela, A., Gercia-Moreno, I., Barosso, J. and Sastre, R. (1998) Laser Performance of Coumarin 540A Dye Molecules in Polymeric Host Media with Different Viscosities: From Liquid Solution to Solid Polymer Matrix. Journal of Applied Physics, 83, 650-660.

[38]  Deshpande, A.V. and Panhalkar, R.R. (2002) Spectroscopic Properties of Coumarin 2 in HCl and HNO3 Catalysed Sol-Gel Glasses. Journal of Luminescence, 96, 185-193.

[39]  Deshpande, A.V. and Kumar, U. (2002) Molecular Forms of Coumarin-307 in Sol-Gel Glasses. Journal of Fluorescence, 16, 679-687.

[40]  Deshpande, A.V., Jathar, L.V. and Rane, J.R. (2008) Effect of Matrix Treatment on Spectroscopic Properties of HCl Catalysed Sol-Gel Glasses Containing Coumarin Laser Dyes. Journal of Fluorescence, 19, 607-614.

[41]  Del Monte, F., Mackenzie, J.D. and Levy, D. (2000) Rhodamine Fluorescent Dimers Adsorbed on the Porous Surface of Silica Gels. Langmuir, 16, 7377-7382.

[42]  Del Monte, F. and Levy, D. (1999) Identification of Oblique and Coplanar Inclined Fluorescent J-Dimers in Rhodamine 110 Doped Sol-Gel-Glasses. Journal of Physical Chemistry B, 103, 8080-8086.

[43]  Del Monte, F. and Levy, D. (1998) Formation of Fluorescent Rhodamine B J-Dimers in Sol-Gel Glasses Induced by the Adsorption Geometry on the Silica Surface. Journal of Physical Chemistry B, 102, 8036-8041.

[44]  Leveau, B., Herlet, N., Livage, J. and Sanchez Chem, C. (1993) Optical Properties of a Near-Infrared Dye Laser Incorporated Inside Sol-Gel Matrices. Chemical Physics Letters, 206, 15-20.

[45]  Del Monte, F. and Levy, D. (1995) Near-Infrared Dyes Encapsulated in Sol-Gel Matrixes. Chemistry of Materials, 7, 292-298.

[46]  Levy, D. and Avnir, D. (1988) Effects of the Changes in the Properties of Silica Cage along the Gel/Xerogel Transition on the Photochromic Behavior of Trapped Spiropyrans. Journal of Physical Chemistry, 92, 4734-4738.

[47]  Narang, U. and Bright, F. (1996) Conformational Flexibility of 1,3-Bis(1-Pyrenyl)Propane Throughout the Sol-Gel to Xerogel Process. Chemistry of Materials, 8, 1410-1414.

[48]  Innozenci, P., Kozuka, H. and Yoko, T. (1997) Fluorescence Properties of the Ru(bpy)32+ Complex Incorporated in Sol-Gel-Derived Silica Coating Films. Journal of Physical Chemistry B, 101, 2285-2291.

[49]  Martini, I., Hartland, G.V. and Kamat, P.V. (1997) Ultrafast Photophysical Investigation of Cresyl Violet Aggregates Adsorbed onto Nanometer-Sized Particles of SnO2 and SiO2. Journal of Physical Chemistry B, 101, 4826-4830.

[50]  Innocenzi, P., Kozuka, H. and Yoko, T. (1996) Dimer-to-Monomer Transformation of Rhodamine 6G in Sol-Gel Silica Films. Journal of Non-Crystalline Solids, 201, 26-36.


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