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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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氨基酸功能化磷钨酸盐的制备及其催化氧化脱硫性能
, PP. 1394-1399
Keywords: l-丙氨酸,磷钨酸,二苯并噻吩,脱硫
Abstract:
？以l-丙氨酸和磷钨酸为原料,合成氨基酸功能化磷钨杂多酸盐([ala]3pw),并采用xrd、ft-ir对其结构进行表征.以[ala]3pw为催化剂,过氧化氢作为氧化剂,甲基咪唑四氟硼酸盐([hmim]bf4)为萃取剂氧化萃取一体法脱除模拟油中的二苯并噻吩(dbt).考察了反应温度、催化剂加入量、o/s物质的量比、萃取剂加入量、硫化物类型等因素对脱硫效率的影响.结果表明,在模拟油为10ml、[ala]3pw=0.04g、o和s的物质的量比为6、v([hmim]bf4)/v(oil)=0.6、反应温度50℃、反应时间180min的条件下,dbt的转化率可达到98.2%.催化剂循环使用4次活性没有明显的降低.
| [1] | 林燕,王芳,张志庆,杨洁,魏颖.离子液体绿色脱硫机理及应用进展[j].化工进展,2013,32(3):549-557.(linyan,wangfang,zhangzhi-qing,yangjie,weiying.mechanismandapplicationofionicliquidsinenvironmentalfriendlyoildesulphurization[j].chemicalindustryandengineeringprogress,2013,32(3):549-557.)
|
| [2] | 郇维芳,欧阳福生.fcc汽油脱硫降烯烃技术最新进展[j].工业催化,2004,12(8):6-10.(xunwei-fang,ouyangfu-sheng.latestadvancesinhydordesulfurizationanolefin-reducingtechniquesforfccgasoline[j].industrialcatalysis,2004,12(8):6-10.)
|
| [3] | 李文秀,崔安磊,范俊刚,孙向乐,张志刚.载铜球形活性炭的制备及其吸附脱硫性能的研究[j].燃料化学学报,2013,41(5):613-618.(liwen-xiu,cuian-lei,fanjun-gang,sunxiang-le,zhangzhi-gang.synthesisofsphericalactivatedcarbonsupportedcoppercatalystanditsperformanceforadsorptivedesulfurization[j].journaloffuelchemistryandtechnology,2013,41(5):613-618.)
|
| [4] | 曾丹林,胡义,王可苗,王光辉.燃料油萃取脱硫技术研究进展[j].石油炼制与化工,2012,43(5):98-102.(zengdan-lin,huyi,wangke-miao,wangguang-hui.researchadvanceindesulfurizationoftransportationfuelsbyextractionprocess[j].petroleumprocessingandpetrochemicals,2012,43(5):98-102.)
|
| [5] | lowh,yanghw,weigt.one-potdesulfurizationoflightoilsbyoxidationandsoluentextractionwithroomtemperatureionicliquids[j].greenchemistry,2003,5:639-642.
|
| [6] | esserj,wasserscheidp,jessa.deepdesulfurizationofoilrefinerystreamsbyextractionwithionicliquids[j].greenchem,2004,3(2):316-322.
|
| [7] | zhangs,zhangq.zhangzc.extractivedesulphurizationanddenitrogenationoffuelsusingionicliquids[j].indengchemres,2004,43(2):614-622.
|
| [8] | 张薇,丁永萍,宫摇敬,宋溪明.羧基功能化离子液体催化二苯并噻吩氧化脱硫[j].燃料化学学报,2012,5(40):628-632.(zhangwei,dingyong-ping,gongyao-jing,songxi-ming.oxidativedesulfurizationofdibenzothiophenecatalysedbycarboxyl-functionalizedionicliquidcmmimbf4[j].journaloffuelchemistryandtechnology,2012,5(40):628-632.)
|
| [9] | 李佳慧,胡嘉,赵荣祥,乔海燕,李秀萍.氯化胆碱/草酸型低共熔溶剂氧化脱除模拟油硫化物[j].燃料化学学报,2014,42(7):870-876.(lijia-hui,hujia,zhaorong-xiang,qiaohai-yan,lixiu-ping.oxidativedesulfurizationofmodeloilwithcholinechloride/oxalicacidasaeutecticsolvent[j].journaloffuelchemistryandtechnology,2014,42(7):870-876.)
|
| [10] | catherinea,genevievec,nicolep,jean-marieb,renet,francoisec,catherineh,henryl.reinvestigationofepoxidationusingtungsten-basedprecursorsandhydrogenperoxideinabiphasemedium[j].inorgchem,1991,30(23):4409-4415.
|
| [11] | 张海燕,代跃利,蔡蕾.杂多酸催化剂催化氧化脱硫研究进展[j].化工进展,2013,32(4):809-815.(zhanghai-yan,daiyue-li,cailei.researchprogressofheteropolyacidcatalyzedoxidativedesulfurization[j].chemicalindustryandengineeringprogree,2013,32(4):809-815.)
|
| [12] | 安莹,陆亮,李才猛,程时富,高国华.磷钼杂多酸离子液体催化氧化脱硫[j].催化学报,2009,30(12):1222-1226.(anying,luliang,licai-meng,chengshi-fu,gaoguo-hua.oxidativedesulfurizationcatalyzedbymolybdophosphate-basedionicliquid[j].chinesejournalofcatalysis,2009,30(12):1222-1226.)
|
| [13] | huangwl,zhuws,lihm,shih,zhugp,liuh,chengy.heteropolyanion-basedionicliquidsfordeepdesulfurizationoffuelsinionicliquids[j].indengchemres,2010,49(19):8998-9003.
|
| [14] | rickertpg,antoniomr,firestonema,kubatkoka,szredert,wishartjf,dietzml.tetraalkylphosphoniumpolyoxometalateionicliquids:novel,organic-inorganichybridmaterials[j].jphyschemb,2007,111(18):4685-4692.
|
| [15] | 刘静,黄小文,赵小平,刘秀梅,颜佩芳,王畅,高艳安.氨基酸功能化杂多酸盐的制备及其在无溶剂条件下催化正十二醇与乙酸酯化反应性能[j].石油学报(石油加工),2013,29(3):383-384.(liujing,huangxiao-wen,zhaoxiao-ping,liuxiu-meng,yanpei-fang,wangchang,gaoyan-an.preparationofaminoacidfuncionalizedheteropolyacidsaltanditscatalyticperformanceforsolvent-freeesterificationofdodecanolwithaceticacid[j].actapetroleisinica(petroleumprocessingsection),2013,29(3):383-384.)
|
| [16] | lul,chengsf,gaojb,gaogh,hemy.deepoxidativedesulfurizationoffuelscatalyzedbyionicliquidinthepresenceofh2o2[j].energyfuels,2007,21(1):383-384.
|
| [17] | 刘日嘉,王睿.氨基化中空sio2杂多化合物复合型催化剂的合成、表征及催化燃油深度脱硫性能[j].高等学校化学学报,2013,34(12):2814-2820.(liuri-jia,wangrui.synthesis,characterizationandcatalyticfuelultra-deepdesulfurizationofhollowamino-sio2supportedheteropolycompoundcatalyst[j].chemicaljournalofchineseuniversities,2013,34(12):2814-2819.)
|
| [18] | 李宇慧,冯丽娟,王景刚,周旋,程斌斌,王晓燕,李春虎.moo3/介孔al2o3催化氧化脱除模拟油中的硫[j].高等学校化学学报,2011,32(3):778-782.(liyu-hui,fengli-juan,wangjing-gang,zhouxuan,chengbin-bin,wangxiao-yan,lichu-hu.catalyticoxidativedesulfurizationofmodeloilbymoo3/mesoporousal2o3[j].chemicaljournalofchineseuniversities,2011,32(3):778-782.)
|
| [19] | luiscc,hildagb,adrianafc,hectord.gg,rogeliocg.oxidativedesulfurizationofsyntheticdieselusingsupportedcatalysts:partiii.supporteffectonvanadium-basedcatalysts[j].cataltoday,2008,133-135:244-254.
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