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-  2015 

添加碳纳米管对钌铱锡氧化物阳极性能的影响
Effect of Carbon Nanotubes on Anodic Properties of Ti/Ru-Ir-Sn Oxides

DOI: 10.13208/j.electrochem.141219

Keywords: 碳纳米管,金属氧化物阳极,电催化活性,强化电解寿命,
carbon nanotubes
,metal oxide anodes,electric catalytic activity,accelerated life

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Abstract:

摘要 本文采用热分解法制备Ti/Ru-Ir-Sn氧化物阳极,运用TGA、SEM、EDS、循环伏安、电化学交流阻抗、极化曲线以及强化电解寿命测试方法,探讨添加不同含量碳纳米管(CNTs)对Ti/Ru-Ir-Sn氧化物阳极的影响规律. 热重分析和阳极能谱数据表明,在烧结温度470 oC条件下CNTs未发生高温氧化分解,仍以单质形式存在阳极涂层中. 与对比样品相比,涂层表面裂纹增多,但仍保持典型形貌. 添加CNTs显著改善了Ti/Ru-Ir-Sn氧化物阳极的电化学性能,增大了阳极的活性表面积,减小了涂层内部电阻,提高了阳极析氯电催化活性,析氯电位增加缓慢,阳极强化电解寿命也得到明显延长. 其中,添加0.1 g·L-1 CNTs的Ti/Ru-Ir-Sn氧化物阳极电催化活性和稳定性最优

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