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Physics  2008 

First order phase transitions in nanoscopic systems

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Abstract:

The problem of first order phase transitions in nanoscopic systems is investigated in the framework of Hill's nanothermodynamics. We obtain the equilibrium conditions and a generalized version of the Clapeyron-Clausius equation for a nanoscopic system which contains two phases. Our study is exemplified for the case when one of the phases consists of an ideal gas.

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