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Catalytic Behaviour of Mesoporous Cobalt-Aluminum Oxides for CO Oxidation

DOI: 10.1155/2014/807545

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Ordered mesoporous materials are promising catalyst supports due to their uniform pore size distribution, high specific surface area and pore volume, tunable pore sizes, and long-range ordering of the pore packing. The evaporation-induced self-assembly (EISA) process was applied to synthesize mesoporous mixed oxides, which consist of cobalt ions highly dispersed in an alumina matrix. The characterization of the mesoporous mixed cobalt-aluminum oxides with cobalt loadings in the range from 5 to 15?wt% and calcination temperatures of 673, 973, and 1073?K indicates that Co2+ is homogeneously distributed in the mesoporous alumina matrix. As a function of the Co loading, different phases are present comprising poorly crystalline alumina and mixed cobalt aluminum oxides of the spinel type. The mixed cobalt-aluminum oxides were applied as catalysts in CO oxidation and turned out to be highly active. 1. Introduction Supported metal oxide catalysts have attracted much attention in recent years due to their widespread applicability in industrially and academically important reactions. The extent and nature of the interaction, dispersion, and reducibility of the metal oxides depend on the synthesis method, loading, calcination temperature, and time. Cobalt supported on alumina is a typical catalyst, which is specially important for Fischer-Tropsch synthesis. Conventionally, the preparation of cobalt catalysts is performed by incipient wetness impregnation using suitable cobalt precursors on commercial alumina at low pH. Weak interaction is normally observed between the positively charged alumina carrier and the cobalt cations resulting in relatively large crystallite sizes [1–4]. Continuous efforts have been made in the last few decades by several groups [5–7] to synthesize porous alumina with high surface area by high-temperature dehydration of bulk powders [8], modified sol-gel synthesis in the presence of organic moieties [9, 10], different surfactants [3], block copolymers [11–14], or evaporation-induced self-assembly (EISA) with colloidal precursors and amine structural agents [15, 16]. These materials represent an active support, which may participate positively or negatively in the formation of the final catalysts. Moreover, the methods of hard templating [17] (carbon template) and microwave irradiation [18] in the presence of surfactants have been applied to synthesize alumina materials with crystalline, ordered, and uniform mesopores. However, this process is very time consuming and hardly scalable for industrial applications. Ordered mesoporous materials


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