Surfactant-grafted
Polyacrylamide (S-PAM), as a new type of oil displacement agent in oilfield,
integrates the advantages of both polymer and surfactant. The oil displacement
experiments using S-PAM in multi-blocks reveal that in-use S-PAMs differ
greatly from ordinary polymers and the physical properties remain unclear. This
is unfavorable to production application and occupational health and safety. This
research compared the physical properties of S-PAMs selected from two producing
area, including specific gravity, particle size and viscosity. The compared
results showed that specific gravity of Lianhua S-PAM was smaller than Haibo
S-PAM; Lianhua S-PAM and Haibo S-PAM accounted for the 93.8% and 80.1% of the
total amount via the particles with 40 mesh and 60 mesh; the viscosity of
Lianhua S-PAM was higher than that of Haibo S-PAM in two S-PAM solutions with
different concentrations.
References
[1]
Wang, D.M., Xia, H.F., Liu, Z.C., et al. (2001) Study of the Mechanism of Polymer Solution with Viscoelastic Behaviour Increasing Microscopicoil Displacement Efficiency and the Forming of Steady “Oil Thread” Flow Channel. SPE68732, Society of Petroleum Engineers.
[2]
Hu, B.Z. (1997) Production Engineering of Polymer Flooding. Petroleum Industry Press, Beijing, 70-72.
[3]
Ge, G.Z., Wang, J.Y. and Wang, Y.L. (2001) Polymer Flooding and Related Chemical Flooding Progress. Oilfield Chemistry, 18, 282-284.
[4]
Parrish, B., Breitenkamp, R.B. and Emrick, T. (2005) PEG- and Peptide-Grafted Aliphatic Polyesters by Click Chemistry. Journal of the American Chemical Society, 127, 7404-7410. http://dx.doi.org/10.1021/ja050310n
[5]
Li, H.Y., Jérome, R., Lecomte, Ph., et al. (2007) Combination of Ring-Opening Polymerization and “Click” Chemistry for the Synthesis of an Amphiphilic Tadpole-Shaped Poly(ε-Caprolactone) Grafted by PEO. Macromolecules, 40, 824-831. http://dx.doi.org/10.1021/ma062488f
[6]
Zhang, J.Y., Zhou, Y.M., Liu, S.Y., et al. (2008) Polyion Complex Micelles Possessing Thermoresponsive Coronas and Their Covalent Core Stabilization via “Click” Chemistry. Macromolecules, 41, 1444-1454.
http://dx.doi.org/10.1021/ma702199f
[7]
Luo, X.L., Wang, G.W., Huang, J.L., et al. (2008) Synthesis of a Novel Kind of Amphiphilic Graft Copolymer with Miktoarm Star-Shaped Side Chains. Macromolecules, 41, 2315-2317. http://dx.doi.org/10.1021/ma800117d
[8]
Hizal, G., Tunca, U., Yagci, Y., et al. (2006) Anthracene-Maleimide-Based Diels-Alder “Click Chemistry” as a Novel Route to Graft Copolymers. Macromolecules, 39, 5330-5336. http://dx.doi.org/10.1021/ma060690c
[9]
Wang, Y.M., Wang, Y.J. and Lu, X.B. (2008) “Grafting-From” Polymerization for Uniformly Bulk Modification of Pre-Existing Polymer Materials via a Supercritical-Fluid Route. Polymer, 49, 474-480.
http://dx.doi.org/10.1016/j.polymer.2007.11.028
[10]
Zhao, J.R., Li, J.Y., Feng, Y., et al. (2007) A Novel Approach to Synthesis of Functional CPVC and CPE or Graft Copolymers—In Situ Chlorinating Graft. Polymers for Advanced Technologies, 18, 822-828.
http://dx.doi.org/10.1002/pat.941