全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Dichloridobis(2-methoxydibenzo[c,e][1,2]oxaphosphorine-κP)platinum(II) trichloromethane solvate

DOI: 10.1107/s1600536809006643

Full-Text   Cite this paper   Add to My Lib

Abstract:

The title compound, [PtCl2(C13H11O2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphosphorine ligands through the metal atom. The PtII ion is in a slightly distorted square-planar environment. The trichloromethane solvent molecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent molecule is linked to the complex molecule via intermolecular bifurcated C—H...Cl and C—H...O hydrogen bonds. The crystal structure is further stabilized by π–π interactions involving the benzene rings, with a centroid–centroid distance of 3.658 (8) .

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133