Each of the Al atoms in the title compound, [Al2(CH3)5(C15H15FNO)], is four-coordinated in a distorted tetrahedral geometry. The dimethylaluminium centre is bound by the N and the O atoms of the (2-dimethylaminophenyl)(2-fluorophenyl)methanolate ligand. The second Al atom is bound by the methanolate O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4 (2):0.6 (2) domain ratio.
