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Di-μ-benzoato-κ3O,O′:O;κ3O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ2N,N′)lead(II)] dihydrate

DOI: 10.1107/s1600536809025896

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Abstract:

The title compound, [Pb2(CH3COO)2(C7H5O2)2(C12H8N2)2]·2H2O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water molecules. Each PbII unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two PbII atoms. The crystal packing is stabilized by O—H...O hydrogen bonds and by π–π interactions between the phen rings of neighboring molecules, with a centroid–centroid distance of 3.577 (3) .

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