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(1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ2S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II)

DOI: 10.1107/s1600536811050550

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Abstract:

The NiII atom in the mononuclear title compound, [Ni(C10H10NS2)(NCS)(C18H15P)], exists within a S2PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN over PPh3.

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