(1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ2S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II)

The NiII atom in the mononuclear title compound, [Ni(C10H10NS2)(NCS)(C18H15P)], exists within a S2PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN over PPh3.