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Molecules  2011 

Proline-Catalysed Amination Reactions in Cyclic Carbonate Solvents

DOI: 10.3390/molecules16043420

Keywords: proline, amination, cyclic-carbonate

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Propylene carbonate is shown to be an environmentally friendly and sustainable replacement for dichloromethane and acetonitrile in proline-catalysed a-hydrazinations of aldehydes and ketones. Enantioselectivities comparable to those obtained in conventional solvents or ionic liquids can be obtained, even when using a lower catalyst loading.


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