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金属学报  2005 

Microstructures Of Rapidly Solidified Cu--Fe Immiscible Alloy
快速凝固Cu-Fe难混溶合金的显微组织

Keywords: Cu-Fe alloy,metastable miscibility gap,liquid-liquid phase transformation,microstructure
Cu—Fe合金
,亚稳液态组元不混溶区,液-液相变,显微组织

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Abstract:

Fine powders of the Cu-Fe alloy were manufactured by using the high-pressure gas atomization technique. The study of the powder microstructures indicated that the size and concentration of the atomized-droplets play important roles in the microstructure evolution. A smaller atomized-droplet has a finer dispersed microstructure. Alloys with composition close to the critical composition of the alloy system are relatively easy to be undercooled into the miscibility gap. The formation of Fe-poor layer on the surface of powder is mainly caused by two reasons. One is the Fe-rich droplets' Marangoni migration towards the center of the atomized-droplet due to the radial temperature gradient, and the other is the repulsive effect of the advancing solid/liquid interface on the Fe-rich droplets.

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