全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Exploring the Catalytic Activity of Zirconia, Zirconia Supported Metals and Metal Oxides for Oxidation of Phenol

DOI: 10.4236/mrc.2012.12004, PP. 23-27

Keywords: Oxidation, Phenol, Bismuth, Platinum, Zirconia

Full-Text   Cite this paper   Add to My Lib

Abstract:

Catalytic oxidation/degradation of phenol with molecular oxygen in aqueous medium by Zirconia, zirconia supported metals and metal oxides at low temperature were studied in a three necked batch reactor. The catalysts prepared were characterized by modern techniques like XRD, SEM and EDX. The activities of different catalysts for the oxidation of phenol in aqueous medium were found to be in the order; Pt-Pd/ZrO2 > Bi-Pt/ZrO2 > Bi-Pd/ZrO2> Pt/ZrO2 > Pd/ZrO2 > Cu/ZrO2> Mn/ZrO2 > Bi/ZrO2. The enhanced catalytic activity of Bi-Pt/ZrO2 is attributed to Bi which in contact with Pt particles promotes its catalytic activity. In short, catalytic oxidation was found to be an effective tool, for the removal of phenol, from industrial waste water.

References

[1]  Imamura, S.: Ind. Eng. Chem. Res. 38 (1999) 1743.
[2]  Wang, R. Qi, Y. Shen, Z. Wu, Z.: Huadong Huagong Xueyuan Xue. 4 (1982) 411.
[3]  Leitenburg, C. Goi, D. Primavera, A. Trovarelli, A. Dolcetti, G.: Appl. Catal. B. 11 (1996) L29.
[4]  Atwater, J. E. Akse, J. R. Mckinnis, J. A. Thompson, J. O.: Appl. Catal. B. 11 (1996) L11.
[5]  Carlo, R. Federico, C. Silvia, B. Ombretta, P. Guido, B.: Appl. Catal. B: Environ. 84 (2008) 678.
[6]  Castro, I. U. Sherrington, D. C. Fortuny, A. Fabregat, A. Stüber, F. Font, J. Bengoa, C.: Catal. Today. 157 (2010) 66.
[7]  Souza, L. D. Subaie, J.S. Richards, R.: J. Colloid Interface Sci. 292 (2005) 476.
[8]  Souza, L. D. Suchopar, A. Zhu, K. Balyozova, D. Devadas, M. Richards, R. M.: Micropor. Mesopor. Mater. 88 (2006) 22.
[9]  Tatibouet, J. M. Guelou, E. Fournier, J.: Topics in Catalysis. 33 (2005) 225.
[10]  Greenberg, A. E. Clesceri, L. S. Eaton, A. D. Standard Methods-For the Examination of Water and Wastewater 18a Ed., Part 5000, 6, APHA-AWWA-WPCF (1992).
[11]  Zhang, Q. Chuang, K.T.: Ind. Eng. Chem. Res. 37 (1998) 3343.
[12]  Resini, C. Catania, F. Berardinelli, S. Paladino, O. Busca, G. Appl Catal B: Environ. 84 (2008) 678.
[13]  Ilyas, M. Sadiq, M.: Chin J Chem. 26 (2008) 941.
[14]  Ilyas, M. Sadiq, M.: Chin. J. Chem. 28 (2010) 2216.
[15]  Bavykin, D. V. Lapkin, A. A. Kolaczkowski, S. T. Plucinski, P. K.: App. Catal. A. 288 (2005) 175.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133