In this study, pseudoboehmite (nano-boehmite) synthesized by A Route Mineral used to adsorb of methylene blue dye solution. The effect of experimental parameters pH, contact time, temperature and initial concentration were studied on adsorption. Results indicated that the optimal pH for adsorption is 10, with the experiments conducted at a temperature of 25?C and adsorption reaches equilibrium after 30 minutes. The optimum adsorbent amount is 0.03 g. The equilibrium data were perfectly represented by the Freundlich isotherm and the adsorption behavior can be better described by pseudo-second-order model.
References
[1]
Salimi, F., Emami, S.S. and Karami, C. (2017) Removal of Methylene Blue from Water Solution by Modified Nano-Boehmite with Bismuth. Inorganic and Nano-Metal Chemistry, 48, 31-40. https://doi.org/10.1080/24701556.2017.1357628
[2]
Rane, N.R., Chandanshive, V.V., Khandare, R.V., Gholave, A.R., Yadav, S.R. and Govindwar, S.P. (2014) Green Remediation of Textile Dyes Containing Wastewater by Ipomoea hederifolia L. RSC Advances, 4, 36623-36632. https://doi.org/10.1039/c4ra06840h
[3]
Wu, Y., Chen, L., Long, X., Zhang, X., Pan, B. and Qian, J. (2018) Multi-Functional Magnetic Water Purifier for Disinfection and Removal of Dyes and Metal Ions with Superior Reusability. Journal of Hazardous Materials, 347, 160-167. https://doi.org/10.1016/j.jhazmat.2017.12.037
[4]
Ai, L., Zhang, C., Liao, F., Wang, Y., Li, M., Meng, L., et al. (2011) Removal of Methylene Blue from Aqueous Solution with Magnetite Loaded Multi-Wall Carbon Nanotube: Kinetic, Isotherm and Mechanism Analysis. Journal of Hazardous Materials, 198, 282-290. https://doi.org/10.1016/j.jhazmat.2011.10.041
[5]
Kamaria, M., Shafieea, S., Salimia, F. and Karami, C. (2019) Comparison of Modified Boehmite Nanoplatelets and Nanowires for Dye Removal from Aqueous Solution. Desalination and Water Treatment, 161, 304-314.
[6]
Pearce, C. (2003) The Removal of Colour from Textile Wastewater Using Whole Bacterial Cells: A Review. Dyes and Pigments, 58, 179-196. https://doi.org/10.1016/s0143-7208(03)00064-0
[7]
Arslan, İ., Balcioǧlu, I.A. and Bahnemann, D.W. (2000) Advanced Chemical Oxidation of Reactive Dyes in Simulated Dyehouse Effluents by Ferrioxalate-Fenton/UV-A and TiO2/UV-A Processes. Dyes and Pigments, 47, 207-218. https://doi.org/10.1016/s0143-7208(00)00082-6
[8]
Sauer, T., Neto, G.C., Jose, H. and Moreira, R. (2002) Kinetics of Photocatalytic Degradation of Reactivedyes in a TiO2 Slurry Reactor. Journal of Photochemistry and Photobiology A: Chemistry, 149, 147-154.
[9]
Srinivasan, A. and Viraraghavan, T. (2010) Decolorization of Dye Wastewaters by Biosorbents: A Review. Journal of Environmental Management, 91, 1915-1929. https://doi.org/10.1016/j.jenvman.2010.05.003
[10]
Ben Younes, S., Bouallagui, Z. and Sayadi, S. (2012) Catalytic Behavior and Detoxifying Ability of an Atypical Homotrimeric Laccase from the Thermophilic Strain Scytalidium Thermophilum on Selected Azo and Triarylmethane Dyes. Journal of Molecular Catalysis B: Enzymatic, 79, 41-48. https://doi.org/10.1016/j.molcatb.2012.03.017
[11]
Salimi, F., Rahimi, H. and Karami, C. (2019) Removal of Methylene Blue from Water Solution by Modified Nanogoethite by Cu. Desalination and Water Treatment, 137, 334-344. https://doi.org/10.5004/dwt.2019.22922
[12]
Yagub, M.T., Sen, T.K., Afroze, S. and Ang, H.M. (2014) Dye and Its Removal from Aqueous Solution by Adsorption: A Review. Advances in Colloid and Interface Science, 209, 172-184. https://doi.org/10.1016/j.cis.2014.04.002
[13]
Park, C., Lee, M., Lee, B., Kim, S., Chase, H.A., Lee, J., et al. (2007) Biodegradation and Biosorption for Decolorization of Synthetic Dyes by Funalia Trogii. Biochemical Engineering Journal, 36, 59-65. https://doi.org/10.1016/j.bej.2006.06.007
[14]
Taha, M., Adetutu, E.M., Shahsavari, E., Smith, A.T. and Ball, A.S. (2014) Azo and Anthraquinone Dye Mixture Decolourization at Elevated Temperature and Concentration by a Newly Isolated Thermophilic Fungus, Thermomucor Indicae-Seudaticae. Journal of Environmental Chemical Engineering, 2, 415-423. https://doi.org/10.1016/j.jece.2014.01.015
[15]
Cornell, R. and Schwertmann, U. (2003) Dissolution, the Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses. 2nd Edition, Wiley-VCH, 297-344.
[16]
Senthil Kumar, P., Sivaranjanee, R., Vinothini, U., Raghavi, M., Rajasekar, K. and Ramakrishnan, K. (2014) Adsorption of Dye onto Raw and Surface Modified Tamarind Seeds: Isotherms, Process Design, Kinetics and Mechanism. Desalination and Water Treatment, 52, 2620-2633. https://doi.org/10.1080/19443994.2013.792016
[17]
Kumar, P.S., Pavithra, J., Suriya, S., Ramesh, M. and Kumar, K.A. (2015) Sargassum wightii, a Marine Alga Is the Source for the Production of Algal Oil, Bio-Oil, and Application in the Dye Wastewater Treatment. Desalination and Water Treatment, 55, 1342-1358. https://doi.org/10.1080/19443994.2014.924032
[18]
Mathivanan, V., Geetha Manjari, S., Ineya, R., Saravanathamizhan, R., Senthil Kumar, P. and Ramakrishnan, K. (2016) Enhanced Photocatalytic Decolorization of Reactive Red by Sonocatalysis Using TiO2 Catalyst: Factorial Design of Experiments. Desalination and Water Treatment, 57, 7120-7129. https://doi.org/10.1080/19443994.2014.983182
[19]
Salimi, F., Eskandari, M. and Karami, C. (2017) Investigation of Methylene Blue Adsorption in Wastewater Using Nano-Zeolite Modified with Copper. Desalination and Water Treatment, 85, 206-214. https://doi.org/10.5004/dwt.2017.21248
[20]
Salimi, F., Tahmasobi, K., Karami, C. and Jahangiri, A. (2017) Preparation of Modified Nano-SiO2 by Bismuth and Iron as a Novel Remover of Methylene Blue from Water Solution. Journal of the Mexican Chemical Society, 61, 250-259. https://doi.org/10.29356/jmcs.v61i3.351
[21]
Alvarez, M., Rueda, E.H. and Sileo, E.E. (2007) Simultaneous Incorporation of Mn and Al in the Goethite Structure. Geochimica et Cosmochimica Acta, 71, 1009-1020. https://doi.org/10.1016/j.gca.2006.11.012
[22]
Crini, G., Lichtfouse, E., Wilson, L.D. and Morin-Crini, N. (2019) Conventional and Non-Conventional Adsorbents for Wastewater Treatment. Environmental Chemistry Letters, 17, 195-213. https://doi.org/10.1007/s10311-018-0786-8
[23]
AbdEl-Salam, A.H., Ewais, H.A. and Basaleh, A.S. (2017) Silver Nanoparticles Immobilised on the Activated Carbon as Efficient Adsorbent for Removal of Crystal Violet Dye from Aqueous Solutions. a Kinetic Study. Journal of Molecular Liquids, 248, 833-841. https://doi.org/10.1016/j.molliq.2017.10.109
[24]
Sadegh, H., Ali, G.A.M., Gupta, V.K., Makhlouf, A.S.H., Shahryari-ghoshekandi, R., Nadagouda, M.N., et al. (2017) The Role of Nanomaterials as Effective Adsorbents and Their Applications in Wastewater Treatment. Journal of Nanostructure in Chemistry, 7, 1-14. https://doi.org/10.1007/s40097-017-0219-4
[25]
Shinde, S.G. and Shrivastava, V.S. (2016) Synthesis of γ-Alumina (Al₂O₃) Nanoparticles and their Potential for Use as an Adsorbent in the Removal of Methylene Blue Dye from Industrial Wastewater. Asian Journal of Chemical and Environmental Research, 9, 129-132.
[26]
Arshadi, M., Mehravar, M., Amiri, M.J. and Faraji, A.R. (2015) Synthesis and Adsorption Characteristics of an Heterogenized Manganese Nanoadsorbent Towards Methyl Orange. Journal of Colloid and Interface Science, 440, 189-197. https://doi.org/10.1016/j.jcis.2014.10.053
[27]
Huang, Q., Liu, M., Chen, J., Wan, Q., Tian, J., Huang, L., et al. (2017) Facile Preparation of Mos2 Based Polymer Composites via Mussel Inspired Chemistry and Their High Efficiency for Removal of Organic Dyes. Applied Surface Science, 419, 35-44. https://doi.org/10.1016/j.apsusc.2017.05.006
[28]
Jiang, Y., Gong, J., Zeng, G., Ou, X., Chang, Y., Deng, C., et al. (2016) Magnetic Chitosan-Graphene Oxide Composite for Anti-Microbial and Dye Removal Applications. International Journal of Biological Macromolecules, 82, 702-710. https://doi.org/10.1016/j.ijbiomac.2015.11.021
[29]
Mishra, D., Anand, S., Panda, R.K. and Das, R.P. (2000) Hydrothermal Preparation and Characterization of Boehmites. Materials Letters, 42, 38-45. https://doi.org/10.1016/s0167-577x(99)00156-1
[30]
Hou, H., Xie, Y., Yang, Q., Guo, Q. and Tan, C. (2005) Preparation and Characterization of γ-ALOOH Nanotubes and Nanorods. Nanotechnology, 16, 741-745. https://doi.org/10.1088/0957-4484/16/6/019
[31]
Wierenga, A., Philipse, A.P., Lekkerkerker, H.N.W. and Boger, D.V. (1998) Aqueous Dispersions of Colloidal Boehmite: Structure, Dynamics, and Yield Stress of Rod Gels. Langmuir, 14, 55-65. https://doi.org/10.1021/la970376z
[32]
Zhang, J., Liu, S., Lin, J., Song, H., Luo, J., Elssfah, E.M., et al. (2006) Self-Assembly of Flowerlike ALOOH (Boehmite) 3D Nanoarchitectures. The Journal of Physical Chemistry B, 110, 14249-14252. https://doi.org/10.1021/jp062105f
[33]
Yaya, I.M., Guillaume, N. and Arkhis, M. (2018) The Synthesis of Mesoporous Pseudo Boehmite by a Route Mineral and Its Transformation into Alumina-γ. Materials Science: An Indian Journal, 16, Article 140.
[34]
Revellame, E.D., Fortela, D.L., Sharp, W., Hernandez, R. and Zappi, M.E. (2020) Adsorption Kinetic Modeling Using Pseudo-First Order and Pseudo-Second Order Rate Laws: A Review. Cleaner Engineering and Technology, 1, Article 100032. https://doi.org/10.1016/j.clet.2020.100032
[35]
Kamari, M., Shafiee, S., Salimi, F. and Karami, C. (2019) Comparison of Modified Boehmite Nanoplatelets and Nanowires for Dye Removal from Aqueous Solution. Desalination and Water Treatment, 161, 304-314. https://doi.org/10.5004/dwt.2019.24295
[36]
Wang, D., Li, Z., Lv, F., Guan, M., Chen, J., Wu, C., et al. (2023) Characterization of Microspheres γ-ALOOH and the Excellent Removal Efficiency of Congo Red. Journal of Physics and Chemistry of Solids, 174, Article 111043. https://doi.org/10.1016/j.jpcs.2022.111043
[37]
Sun, Y., Ding, C., Cheng, W. and Wang, X. (2014) Simultaneous Adsorption and Reduction of U(VI) on Reduced Graphene Oxide-Supported Nanoscale Zerovalent Iron. Journal of Hazardous Materials, 280, 399-408. https://doi.org/10.1016/j.jhazmat.2014.08.023
[38]
Khan, H., Iram, Gul, K., Ara, B., Khan, A., Ali, N., et al. (2020) Adsorptive Removal of Acrylic Acid from the Aqueous Environment Using Raw and Chemically Modified Alumina: Batch Adsorption, Kinetic, Equilibrium and Thermodynamic Studies. Journal of Environmental Chemical Engineering, 8, Article 103927. https://doi.org/10.1016/j.jece.2020.103927
[39]
Sheng, G., Li, J., Shao, D., Hu, J., Chen, C., Chen, Y., et al. (2010) Adsorption of Copper (II) on Multiwalled Carbon Nanotubes in the Absence and Presence of Humic or Fulvic Acids. Journal of Hazardous Materials, 178, 333-340. https://doi.org/10.1016/j.jhazmat.2010.01.084
[40]
Ciopec, M., Davidescu, C.M., Negrea, A., Grozav, I., Lupa, L., Negrea, P., et al. (2012) Adsorption Studies of Cr(iii) Ions from Aqueous Solutions by DEHPA Impregnated onto Amberlite XAD7—Factorial Design Analysis. Chemical Engineering Research and Design, 90, 1660-1670. https://doi.org/10.1016/j.cherd.2012.01.016
[41]
Perwitasari, D.S., Pracesa, Y.A.Y., Pangestu, M.A. and Tola, P.S. (2021) Langmuir and Freundlich Isotherm Approximation on Adsorption Mechanism of Chrome Waste by Using Tofu Dregs. 2nd International Conference Eco-Innovation in Science, Engineering, and Technology, Samara, 11 December 2021, 106-112. https://doi.org/10.11594/nstp.2021.1417
[42]
Mve, M.Z., Mba, C.M.M., Eba, F. and Ondo, J.A. (2020) Study of the Adsorption Equilibrium of the Methylene blue from Aqueous Solution onto Activated Carbon of Coula Edulis Nut Shells. Research Journal of Chemistry and Environment, 24, 40-50.
[43]
Danesh, N., Hosseini, M., Ghorbani, M. and Marjani, A. (2016) Fabrication, Characterization and Physical Properties of a Novel Magnetite Graphene Oxide/Lauric Acid Nanoparticles Modified by Ethylenediaminetetraacetic Acid and Its Applications as an Adsorbent for the Removal of Pb(ii) Ions. Synthetic Metals, 220, 508-523. https://doi.org/10.1016/j.synthmet.2016.07.025