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-  2018 

水溶性大豆多糖体外吸附Pb2+的研究

DOI: 10.3969/j.issn.1673-1689.2018.04.008

Keywords: 大豆多糖 Pb2+ 等温吸附 动力学 金属选择性
SSPS
,Pb2+,binding isotherms,kinetics,metal selectivity

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Abstract:

以水溶性大豆多糖(SSPS)为吸附剂,改变pH、吸附时间、初始Pb2+浓度、加入人体必需金属元素(Ca2+,Mg2+,Zn2+,Cu2+)探究其体外吸附Pb2+的规律性质。结果表明:适宜吸附的pH范围为4~6;等温吸附曲线符合Langmuir单层吸附模型;动力学实验表明初始Pb2+质量浓度为25 mg/L和50 mg/L时符合准一级动力学方程,初始Pb2+质量浓度为100 mg/L时符合准二级动力学方程。大豆多糖对Pb2+的选择性优于Zn2+和Mg2+,其清除Pb2+的同时可避免有益微量元素Zn2+和Mg2+的过度损失,是一种安全的Pb2+吸附剂。
Soybean soluble polysaccharides(SSPS),was evaluated for possible use as a kind of heavy metals adsorbent. In vitro binding of lead as affected by pH,contact time,metal concentration,and essential metals was carried out in a batch mode. The results indicated that the suitable range of pH was 4~6,lead binding isotherm was well described by Langmuir model at pH 5.5. Kinetics at low concentrations(25、50 mg/L) and high metal concentrations(100 mg/L) obeyed pseudo-first-order model and pseudo-second-order model,respectively. SSPS showed a higher selectivity toward Pb2+ than Zn2+ and Mg2+. Thus SSPS can be used as a safe detoxifying agent for Pb2+ which preventing the loss of essential metals(Zn2+ and Mg2+) successfully

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