激光诱导击穿光谱技术研究进展
Research Progress on Laser Induced Breakdown Spectroscopy

DOI: 10.12677/OE.2016.62012, PP. 75-81

Keywords: 激光诱导击穿光谱，等离子体，自吸收效应
Laser-Induced Breakdown Spectroscopy, Plasma, Self-Absorption Effect

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Abstract:

激光诱导击穿光谱技术是激光技术的重大发明，因其能够对物质元素进行无损、高灵敏度、快速的定性与定量分析，成为污染物检测、食品安全检测、元素痕量分析等领域重要的技术手段。经过多年发展，激光诱导击穿光谱技术以其具有的独有技术优势，在多个领域表现出了巨大的潜在应用价值，并且国外同行已将这项技术应用到核电站安全监控、空间探索、工业检测等领域。相对于国外的研究进展，国内开展此项技术的研究起步较晚，尤其在应用领域存在较大差距。本文综述激光诱导击穿光谱技术的发展历程，概述该技术的基本原理，突出应用领域及其特点，并分析对检测结果的影响因素。
Laser-induced breakdown spectroscopy is an important invention. It has the characteristics of no damage, high sensitivity and rapid qualitative and quantitative analysis of material elements, so it has been widespread concern of pollutant monitoring, food safety inspection and trace element analysis etc. After years of development, the technology of laser-induced breakdown spectroscopy (LIBS) is given many technical advantages in the field of multiple with potential appliance value. The LIBS has been widely used abroad, such as nuclear power plant safety monitoring, space exploration and industrial inspection etc. However, study on LIBS in China started late; especially in the field of application, there is a big gap. It described the development of laser-induced breakdown spectroscopy, basic principles, application field and characteristics, and analysed the impact factors of testing result.

References

[1]	Brech, F. and Cross, L. (1962) Optical Microemission Stimulated by a Ruby Laser. Applied Spectroscopy, 16, 59-64.
[2]	Runge, E.F., Bonfiglio, S. and Bryan, F.R. (1966) Spectrochemical Analysis of Molten Metal Using a Pulsed Laser Source. Spectrochim Acta, 22, 1678-1680.
[3]	王春龙, 刘建国, 赵南京, 马明俊, 王宴, 胡丽, 张大海, 余洋, 孟德硕, 章炜, 刘晶, 张玉钧, 刘文清. 基于支持向量有机回归的水体重金属激光诱导击穿光谱定量分析研究[J]. 光学学报, 2013, 33(3): 0330002.
[4]	Giussani, B., Monticelli, D. and Rampazzi, L. (2009) Role of Laser Ablation-Inductively Coupled Plasma-Mass Spec- trometry in Cultural Heritage Research: A Review. Analytica Chimica Acta, 635, 6-21.
[5]	Kumar, A. and Sharma, P.C. (2006) Uses of LIBS Technology in Biological Media. Optics East, International Society for Optics and Photonics, 637701.
[6]	董美蓉, 陆继东, 李军, 陈凯, 潘圣华, 姚顺春, 李俊彦. 液相和固相钢铁的激光诱导击穿光谱特性[J]. 光学学报, 2011, 31(1): 0130002.
[7]	张大成, 马新文, 朱小龙, 李斌, 祖凯玲. 激光诱导击穿光谱应用于三种水果样品微量元素的分析[J]. 物理学报, 2008, 57(10): 6348-6353.
[8]	Lidiane, C.N., Gilmare, A.D.S., Lilian, C.T., Dario, S.J., Ronei, J.P. and Francisco, J.K. (2009) Simultaneous Opti- mization by Neuro-Genetic Approach for Analysis of Plant Materials by Laser Induced Breakdown Spectroscopy. Spectrochimica Acta Part B, 64, 565-572.
[9]	Lanza Nina, L., Wiens Roger, C., Clegg Samuel, M., Ollila Ann, M., Humphries Seth, D., Newsom Horton, E. and Barefield James, E. (2010) Calibrating the Chemcam Laser-Induced Breakdown Spectroscopy Instrument for Carbo- nate Minerals on Mars. Applied Optics, 49, C211-C217.
[10]	胡志裕, 张雷, 尹王保, 马维光, 董雷, 贾锁堂. 激光诱导击穿光谱在燃煤电厂及土壤污染物在线检测中的应用研究[J]. 大气与环境光学学报, 2013, 8(1): 26-35.
[11]	谢承利, 陆继东, 李勇, 林兆祥. 用LIBS方法测量铝合金中的合金元素[J]. 华中科技大学学报: 自然科学版. 2008, 36(10): 114-117.
[12]	Gaudiuso, R., Dell’Aglio, M., Pascale, O.D., Senesi, G.S. and Giacomo, A.D. (2010) Laser Induced Breakdown Spectroscopy for Elemental Analysis in Environmental, Cultural Heritage and Space Applications: A Review of Methods and Results. Sensors, 10, 7434-7468.
[13]	鲁翠萍, 刘文清, 赵南京, 刘立拓, 陈东, 张玉钧, 刘建国. 土壤重金属铬元素的激光诱导击穿光谱定量分析研究[J]. 物理学报, 2011, 60(4): 045206.
[14]	Yamamoto, K.Y., Cremers, D.A., Ferris, M.J. and Foster, L.E. (1996) Detection of Metals in the Environment Using a Portable Laser-Induced Breakdown Spectroscopy Instrument. Applied Spectroscopy, 50, 222-233.
[15]	Yoon, Y., Kim, T., Yang, M., Lee, K. and Lee, G. (2001) Quantitative Analysis of Pottery Glaze by Laser Induced Breakdown Spectroscopy. Microchemical Journal, 68, 251-256.
[16]	Arca, G., Ciucci, A., Palleschi, V., Rastelli, S. and Tognoni, E. (1997) Trace Element Analysis in Water by the Laser-Induced Breakdown Spectroscopy Technique. Applied Spectroscopy, 51, 1102-1105. http://dx.doi.org/10.1366/0003702971941863
[17]	孙兰香, 于海斌, 丛智博, 辛勇. 利用LIBS技术在线半定量分析液态钢成分[J]. 仪器仪表学报, 2011, 32(11): 2602-2608.
[18]	Hanafi, M., Omar, M.M. and Garnal, Y.E.E.-D. (2000) Study Oflaser-Induced Breakdown Spectroscopy of Gases. Radiation Physics and Chemistry, 57, 11-20. http://dx.doi.org/10.1016/S0969-806X(99)00344-8
[19]	McNaghten, E.D., Parkes, A.M., Griffith, B.C., Whitehouse, A.I. and Palanco, S. (2009) Detection of Trace Concentrations of Helium and Argon in Gas Mixtures by Laser-Induced Breakdown Spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy, 64, 1111-1118. http://dx.doi.org/10.1016/j.sab.2009.07.011
[20]	Lazzari, C., De Rosa, M., Rastelli, S., Ciucci, A., Pallesch, V. and Salvetti, A. (1994) Detection of Mercury in Air by Time-Resolved Laser-Induced Breakdown Spectroscopy Technique. Laser and Particle Beams, 12, 525-530. http://dx.doi.org/10.1017/S0263034600008387
[21]	Zhang, H.S., Singh, J.P., Yuen, F.-Y. and Cook, R.L. (1995) Laser-Induced Breakdown Spectra in a Coal-Fried MHD Facility. Applied Spectroscopy, 49, 1617-1623. http://dx.doi.org/10.1366/0003702953965759
[22]	Vass, A.A., Madhavi, M., Synstelien, J. and Collins, K. (2005) Elemental Characterization of Skeletal Remains Using Laser-Induced Breakdown Spectroscopy (LIBS). Proceedings of the 57th Annual Meeting of the American Academy of Forensic Sciences, 21-26.
[23]	Hybl, J.D., Lithgow, G.A. and Buckley, S.G. (2003) Laser-Induced Breakdown Spectroscopy Detection and Classification of Biological Aerosols. Applied Spectroscopy, 57, 1207-1215. http://dx.doi.org/10.1366/000370203769699054
[24]	Samek, O., Beddows, D.C.S., Telle, H.H., Kaiser, J., Li？ka, M., Cáceres, J.O. and Ure？a, A.G. (2001) Quantitative Laser-Induced Breakdown Spectroscopy Analysis of Calcified Tissue Samples. Spectrochimica Acta Part B: Atomic Spectroscopy, 56, 865-875. http://dx.doi.org/10.1016/S0584-8547(01)00198-7
[25]	Kumar, A., Yueh, F.-Y., Singh, J.P. and Burgess, S. (2004) Characterization of Malignant Tissue Cells by Laser-In- duced Breakdown Spectroscopy. Applied Optics, 43, 5399-5403. http://dx.doi.org/10.1364/AO.43.005399
[26]	Tamura, K., Peterson, D., Peterson, N., Scecher, G., Nei, M. and Kumar, S. (2011) MEGA5: Molecular Evolutionary Genetics Analysis Using Maximum Likelihood, Evolutionary Distance, and Maximum Parsimony Methods. Molecular Biology and Evolution, 28, 2731-2739. http://dx.doi.org/10.1093/molbev/msr121
[27]	Baudelet, M., Yu, J., Bossu, M., Jovelet, J., Wolf, J.P., Amodeo, T., Frejafor, E. and Laloi, P. (2006) Discrimination of Microbiological Samples Using Femtosecond Laser-Induced Breakdown Spectroscopy. Applied Physics Letters, 89, Article ID: 163903. http://dx.doi.org/10.1063/1.2361270
[28]	Singh, V.K., Singh, V., Rai, A.K., Thakur, S.N., Rai, P.K. and Singh, J.P. (2008) Quantitative Analysis of Gallstones Using Laser-Induced Breakdown Spectroscopy. Applied Optics, 47, G38-G47. http://dx.doi.org/10.1364/AO.47.000G38
[29]	吴金泉, 林兆祥, 刘林美, 常亮. 藏药七十味珍珠丸的激光诱导击穿光谱检测[J]. 中南民族大学学报(自然科学版), 2009, 25(2): 53-56.
[30]	Sallé, B., Cremers, D.A., Maurice, S. and Wiens, R.C. (2005) Laser-Induced Breakdown Spectroscopy for Space Exploration Applications: Influence of the Ambient Pressure on the Calibration Curves Prepared from Soil and Clay Samples. Spectrochimica Acta Part B: Atomic Spectroscopy, 60, 479-490. http://dx.doi.org/10.1016/j.sab.2005.02.009
[31]	邵妍, 张艳波, 高勋, 杜闯. 林景全. 激光诱导击穿光谱技术的研究与应用新进展[J]. 光谱学与光谱分析, 2013, 33(10): 2593-2598.
[32]	Liu, Y.M., Singha, S., Witt, T.E., Cheng, Y.T. and Gordon, R.J. (2008) Observation of Near Total Polarization in the Ultrafast Laser Ablation of Si. Applied Physics Letters, 93, Article ID: 161502. http://dx.doi.org/10.1063/1.3000966
[33]	季振国, 李铁强, 席俊华, 毛启楠. 激光诱导击穿光谱及其在元素分析中的应用[J]. 材料科学与工程学报, 2011, 29(3): 455-460+428.
[34]	Moon, H.-Y., Herrera, K.K., Omenetto, N., Smith, B.W. and Winefordner, J.D. (2009) On the Usefulness of Adup- licating Mirror to Evaluate Self-Absorption Effects in Laser Induced Breakdown Spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy, 64, 702-713. http://dx.doi.org/10.1016/j.sab.2009.06.011
[35]	Piscitelli, V., Martine, M.A., Fernández, A.J., González, J.J., Mao, X.L. and Russo, R.E. (2009) Double Pulse Laser Induced Breakdown Spectroscopy: Experimental Study of Lead Emission Intensity Dependence on the Wavelengths and Sample Matrix. Spectrochimica Acta Part B: Atomic Spectroscopy, 64, 147-154. http://dx.doi.org/10.1016/j.sab.2008.11.008
[36]	Vrenegor, J., Noll, R. and Sturm, V. (2005) Investigation of Matrix Effects in Laser-Induced Breakdown Spectroscopy Plasmas of High-Alloy Steel for Matrix and Minor Elements. Spectrochimica Acta Part B: Atomic Spectroscopy, 60, 1083-1091. http://dx.doi.org/10.1016/j.sab.2005.05.027
[37]	Herrera, K.K., Tognoni, E., Gornushkin, I.B., Omenetto, N., Smith, B.W. and Winefordner, J.D. (2009) Comparative Study of Two Standard-Free Approaches in Laser-Induced Breakdown Spectroscopy as Applied to the Quantitative Analysis of Aluminum Alloy Standards under Vacuum Conditions. Joural of Analytical Atomic Spectrometry, 24, 426- 438. http://dx.doi.org/10.1039/b820494b
[38]	宋一中, 李亮. 激光诱导Al等离子体连续辐射的时间分布[J]. 光学学报, 2001, 21(4): 404-409.
[39]	孙兰香, 于海斌, 郭前进, 丛智博, 杨志家. 激光诱导击穿光谱在物质成分定量分析方面的实验研究进展[J]. 仪器仪表学报, 2008, 29(10): 2235-2240.
[40]	郑贤锋, 唐晓闩, 凤尔银, 杨锐, 季学韩, 崔执凤. 缓冲气体对激光等离子体光谱特征影响的实验研究[J]. 原子与分子物理学报, 2002, 19(3): 267-271.

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