OALib Journal期刊
ISSN: 2333-9721
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含pdms侧链的水性聚氨酯的制备及性能研究
Keywords: 水性聚氨酯,aeappdms,耐水性
Abstract:
?以异佛尔酮二异氰酸酯(ipdi)、聚酯二元醇(pcl)、二羟甲基丙酸(dmpa)、三乙胺(tea)、乙二胺(eda)、氨乙基氨丙基聚二甲基硅氧烷(aeappdms)等为原料,采用二次自乳化法,合成系列含pdms侧链的改性水性聚氨酯(sipu)。探讨了aeappdms含量对乳液粒径、黏度与涂膜耐水性、机械强度的影响。结果表明:改性后的水性聚氨酯综合性能良好,水性聚氨酯的主链上引入pdms侧链导致涂膜的吸水率显著下降。
References
[1] | piotrkrl.synthesismethods,chemicalstructuresandphasestructuresoflinearpolyurethanes.propertiesandapplicationsoflinearpolyurethanesinpolyurethaneelastomers,copolymersandionomers[j].progressinmaterialsscience,2007,52(6):915-1015.
|
[2] | xiaolizhua,mengzhang,qingsizhang,etal.synthesisandcharacterizationofbis(methoxylhydroxyl)-functionalizeddisiloxaneandpolysiloxaneoligomersderivativestherefrom[j].europeanpolymerjournal,2005,41(9):1993-2001.
|
[3] | 侯孟华,刘伟区,陈精华,等.氨基硅油改性水性聚氨酯涂料的研究[j].化学建材,2005,19(6):20-22.
|
[4] | carlbw,stuartlc.morphologyandpropertiesofsegmentedpolyetherpolyurethaneureas[j].macromolecules,1983(16):775-786.
|
[5] | zhangchuyin,zhangxingyuan,daijjabing,etal.synthesisandpropertiesofpdmsmodifiedwaterbornepolyurethane-acrylichybridemulsionbysolvent-freemethod[j].progressinorganiccoatings,2008,63(2):238-244.
|
[6] | 黄勤,张剑秋,封玉凤.高固含量有机硅改性水性聚氨酯乳液的制备及性能研究[j].涂料工业,2006,36(9):26-29.
|
[7] | chenhong,fanquli,dongzhongchen,etal.synthesisandpropertiesofpolyurethanemodifiedwithanaminoethylaminoporpyl-substitutedpoly-dimethylsiloxnae[j].jounalofappliedpolymerscience,2001,79(2):295-301.
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