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热力发电  2015 

富氧燃烧烟气中汞的氧化机理研究进展

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Keywords: 富氧燃烧,污染物排放,烟气组分,汞析出形态,氧化机理

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Abstract:

富氧燃烧是控制co2排放最有效的技术之一。了解富氧燃烧气氛下汞析出形态规律,特别是在煤富氧燃烧气氛下,高h2o和co2含量对烟气中主要氧化性组分(so3,so2,no,no2,hcl,o2,co)间化学反应的作用,以及反应产物和组分与hg0间的相互影响规律,是解决随着富氧燃烧新技术的应用而出现汞控制问题的关键。对此,本文通过查阅相关文献总结分析发现:由于不同燃烧过程会造成烟气组分不同,hg0与不同烟气组分间的反应机理以及hg0的形态转变机制均会对hg0的控制方式造成根本影响。同时指出,对于富氧燃烧模式下的新烟气构成,在常规煤燃烧烟气组分基础上建立的汞排放规律、机制与机理等可能不再适用。

References

[1]  吴天翔.试论选煤在发展低碳经济中的作用[j].选煤技术,2011(5):79-80.wutianxiang.trytodiscusstheeffectofcoalpreparationinthedevelopmentoflowcarboneconomy[j].coalpreparationtechnology,2011(5):79-80.
[2]  刘志国.专家表示我国应大力实施洁净煤战略[n].人民政协报,2011-10-24.liuzhiguo.theexpertreckonedthatchinavigorouslyimplementthestrategyofcleancoal[n].people'spoliticalconsultativeconferencenewspaper,2011-10-24.
[3]  streetsdg,haojm,wuy,etal.anthropogenicmercuryemissionsinchina[j].atmosphericenvironment,2005,39:7789-7806.
[4]  usepa,nationalemissionstandardsforhazardousairpollutantsfromcoal-andoil-firedelectricutilitysteamgeneratingunitsandstandardsofperformanceforfossil-fuel-firedelectricutility,industrial-commercial-institutional,andsmallindustrial-commercial-institutionalsteamgeneratingunits[s].40cfr(codeoffederalregulations)parts60and63,2011.
[5]  杨立国,段玉锋,范晓旭.汞在燃煤固态产物中的富集规律及其影响因素[j].燃烧科学与技术,2010,16(6):485-490.yangliguo,duanyufeng,fanxiaoxu.enrichmentcharacteristicsofmercuryinsolidproductsofcoal-firedpowerplantsandinfluencingfactors[j].journalofcombustionscienceandtechnology,2010,16(6):485-490.
[6]  谭增强,邱建荣,向军,等.氯化锌改性竹炭脱除单质汞的特性与机理分析[j].化工学报,2011,62(7):1944-1950.tanzengqiang,qiujianrong,xiangjun,etal.performanceandmechanismforelementalmercuryremovalbybamboocharcoalmodifiedbyzncl2[j].chemicalindustryandengineeringsocietyofchinajournal,2011,62(7):1944-1950.
[7]  陶叶,禚玉群,刘晶,等.燃煤烟气中汞均相氧化的数值模拟[j].化工学报,2011,62(1):186-191.taoye,zhuoyuqun,liujing,etal.numericalmodelingofmercuryhomogeneousoxidationincoal-firedfluegas[j].chemicalindustryandengineeringsocietyofchinajournal,2011,62(1):186-191.
[8]  钟丽萍,曹晏,李文英,等.燃煤电厂污染控制单元对汞释放的控制作用[j].燃料化学学报,2010,38(6):641-646.zhongliping,caoyan,liwenying,etal.effectoftheexistingairpollutantcontroldevicesonmercuryemissionincoal-firedpowerplants[j].journaloffuelchemistryandtechnology,2010,38(6):641-646.
[9]  gb13223-2011,火电厂大气污染物排放标准[s].gb13223-2011,emissionstandardofairpollutantsforthermalpowerplants[s].
[10]  hadjipaschalisi,kourtisg,poullikkasa.assessmentofoxy-fuelpowergenerationtechnologies[j].renewableandsustainableenergyreviews,2009,13(9):2637-2644.
[11]  toftegaardmb,brixj,jensenpa,etal.oxy-fuelcombustionofsolidfuels[j].progressinenergyandcombustionscience,2010,36(5):581-625.
[12]  doe.advancedcarbondioxidecapturer&dprogram:technologyupdate[r].2011.
[13]  王长安,车德福.o2/co2燃烧技术进展1:燃烧与传热特性[j].热力发电,2011,40(5):10-15.wangchang'an,chedefu.progressinresearchofo2/co2combustiontechnologyi:combustionandheattransferbehavior[j].thermalpowergeneration,2011,40(5):10-15.
[14]  王长安,车德福.o2/co2燃烧技术进展2:污染物排放特性与经济性分析[j].热力发电,2011,40(5):15-19.wangchang'an,chendefu.progressinresearchofo2/co2combustiontechnologyii:pollutantemissionbehaviorandeconomicefficiencyanalysis[j].thermalpowergeneration,2011,40(5):15-19.
[15]  陈传敏,赵长遂,庞克亮,等.o2/co2气氛下燃煤过程中nox排放特性实验研究[j].东南大学学报(自然科学版),2005,35(5):738-741.chenchuanmin,zhaochangsui,pangkeliang,etal.experimentsofnoxemissioncharacteristicsduringcoalcombustionundero2/co2atmosphere[j].journalofsoutheastuniversity(naturalscienceedition),2005,35(5):738-741.
[16]  normannf,anderssonk,lecknerb,eta1.hightemperaturereductionofnitrogenoxidesinoxy-fuelcombustion[j].fuel,2008,87(17/18):3579-3585.
[17]  normannf,anderssonk,lecknerb,eta1.emissioncontrolofnitrogenoxidesintheoxy-fuelprocess[j].progressinenergyandcombustionscience,2009,35(5):385-397.
[18]  fuente-cuestaa,loópez-antoónma,díaz-somoanom,etal.retentionofmercurybylow-costsorbents:influenceoffluegascompositionandflyashoccurrence[j].chemicalengineeringjournal,2012,213:16-21.
[19]  rodríguez-pe�rezj,loópez-antoónma,díaz-somoanom,etal.regenerablesorbentsformercurycaptureinsimulatedcoalcombustionfluegas[j].journalofhazardousmaterials,2013,260:869-877.
[20]  abad-vallep,loópez-antoónma,díaz-somoanom,etal.theroleofunburnedcarbonconcentratesfromflyashesintheoxidationandretentionofmercury[j].chemicalengineeringjournal,2011,174:86-92.
[21]  anhedenm,yanj,desmedtg.denitrogenation(oroxyfuelconcepts)[j].oil&gasscienceandtechnology-revuedifpenergiesnouvelles,2005,60:485-495.
[22]  stangerr,wallt.sulphurimpactsduringpulverizedcoalcombustioninoxy-fueltechnologyforcarboncaptureandstorage[j].progressinenergyandcombustionscience,2011,37:69-88.
[23]  koornneefj,ramireza,vanharmelent,etal.theimpactofco2captureinthepowerandheatsectorontheemissionofso2,nox,particulatematter,volatileorganiccompoundsandnh3intheeuropeanunion[j].atmosphericenvironment,2010,44:1369-1385.
[24]  croisete,thambimuthukv,palmera.acoalcombustionino2/co2mixturescomparedwithair[j].canadianjournalofchemicalengineering,2000,78:402-407.
[25]  croisete,thambimuthukv.noxandso2emissionfromo2/co2recycledcoalcombustion[j].fuel,2001,80:2117-2121.
[26]  niksas,helblejj,fujiwaran.kineticmodelingofhomogeneousmercuryoxidation:theimportanceofnoandh2oinpredictingoxidationincoal-derivedsystems[j].environmentalscienceandtechnology,2001,35:3701-3706.
[27]  liush,yannq,liuzr,etal.usingbrominegastoenhancemercuryremovalfromfluegasofcoal-firedpowerplants[j].environmentalscienceandtechnology,2007,41:1405-1412.
[28]  nuriafm,lopez-antonma,díaz-somoanom,etal.effectofoxy-combustionfluegasonmercuryoxidation[j].environmentalscienceandtechnology,2014,48:7164-7170.
[29]  drangaba,lazarl,koeserh.oxidationcatalystsforelementalmercuryinfluegases:areview[j].catalysts,2012,2:139-170.
[30]  griffinrd.anewtheoryofdioxinformationinmunicipalsolidwastecombustion[j].chemosphere,1986,15:1987-1990.
[31]  sniderg,ariyap.photo-catalyticoxidationreactionofgaseousmercuryovertitaniumdioxidenanoparticlesurfaces[j].chemicalphysicsletters,2010,491:23-28.
[32]  wanghq,zhousy,xiaol,etal.titaniananotubes――auniquephotocatalystandadsorbentforelementalmercuryremoval[j].catalysistoday,2011,175:202-208.
[33]  kokb,byuny,chom,etal.influenceofhclonoxidationofgaseouselementalmercurybydielectricbarrierdischargeprocess[j].chemosphere,2008,71:1674-1682.
[34]  wangzh,jiangsd,zhuyj,etal.investigationonelementalmercuryoxidationmechanismbynon-thermalplasmatreatment[j].fuelprocessingtechnology,2010,91:1395-1400.
[35]  zhaoy,mannmd,olsones,etal.effectsofsulphurdioxideandnitricoxideonmercuryoxidationandreductionunderhomogeneousconditions[j].journaloftheair&wastemanagementassociation,2006,56,628-635.
[36]  howerjc,seniorcl,subergem,etal.mercurycapturebynativeflyashcarbonsincoal-firedpowerplants[j].progressinenergyandcombustionscience,2010,36:510-529.
[37]  刘彦,韦宏敏,徐江荣,等.o2/co2与空气对燃煤汞形态分布的影响[j].中国电机工程学报,2008,28(11):48-53.liuyan,weihongmin,xujiangrong,etal.effectofo2/co2andaironmercuryspeciationincoalfiredfluegas[j].proceedingsofthecsee,2008,28(11):48-53.
[38]  吴辉,邱建荣,王泉海,等.氧基燃烧方式下燃煤汞析出规律的初步试验研究[j].工程热物理学报,2007,28(增刊2):185-188.wuhui,qiujianrong,wangquanhai,etal.preliminaryexperimentalresearchofthemercurytransformationduringoxy-fuelcoalcombustion[j].journalofengineeringthermophysics,2007,28(suppl.2):185-188.
[39]  吴辉,邱建荣,曾汉才,等.o2/co2燃烧方式下燃煤hg排放试验研究[j].热能动力工程,2010,25(4):427-431.wuhui,qiujianrong,zenghancai,etal.experimentalresearchofthehgemissionduringcoalcombustionundero2/co2combustionmode[j].journalofengineeringforthermalenergyandpower,2010,25(4):427-431.
[40]  王泉海,邱建荣,温存,等.氧燃烧方式下痕量元素形态转化的试验和模拟研究[j].工程热物理学报,2006,27(增刊2):199-202.wangquanhai,qiujianrong,wencun,etal.aexperimentalandsimulativestudyonthemorphologicaltransformationofthetraceelementunderoxy-fuelcombustionatmosphere[j].journalofengineeringthermophysics,2006,27(suppl.2):199-202.
[41]  王泉海,邱建荣,温存,等.氧燃烧方式下痕量元素形态转化的热力学平衡模拟[c]//中国工程热物理学会第十一届年会燃烧学学术会议文集.北京:2005:642-646.wangquanhai,qiujianrong,wencun,etal.athermodynamicequilibriumsimulationoftransformationoftraceelementsformunderoxygencombustionmode[c]//proceedingoftheeleventhannualmeetingatthechineseacademyofengineeringthermalphysicscombustionconference.beijing,2005:642-646.
[42]  gerdemanns,summersc,oryshchynd,etal.developmentsinintegratedpollutantremovalforlow-emissionoxy-fuelcombustion[r].doe/arc-2005-026.
[43]  ochs,tom,patrickb,etal.proofofconceptforintegratingoxy-fuelcombustionandtheremovalofallpollutantsfromacoalfiredflame[c]//proceedingsofthe30thinternationaltechnicalconferenceoncoalutilizationandfuelsystems:coaltechnologyassociation,2005.
[44]  ochst.anintegratedapproachforemissionscaptureandsequestrationinaconventionalfossilfueledpowerplant[r].internaldoereport,2004.
[45]  suriyawonga.oxy-coalcombustion:submicrometerparticleformation,mercuryspeciation,andtheircapture[d].washingtonuniversity:universityofmissouri-saintlouis(st.louis),2009.
[46]  suniyawonga,gamblem,leem,etal.submicrometerparticleformationandmercuryspeciationundero2-co2coalcombustion[j].energy&fuels,2006,20:2357-2363.
[47]  gharebaghim,hugheskj,porterrtj,etal.mercuryspeciationinair-coalandoxy-coalcombustion:amodellingapproach[j].proceedingsofthecombustioninstitute,2011,33:1779-1786.
[48]  苑奇.美国燃煤电厂一体化脱汞技术进展[j].中国电力,2011,44(11):50-54.yuanqi.developmentofintegratedmercurycapturetechnologyatcoal-firedpowerplantinusa[j].electricpower,2011,44(11):50-54.
[49]  殷立宝,高正阳,钟俊.燃煤电厂脱硫石膏汞形态及热稳定性分析[j].中国电力,2013,46(9):145-149.yinlibao,gaozhengyang,zhongjun,etal.analysisofmercuryspeciesandthermalstabilityofdesulphrizedgypsumincoal-firedboiler[j].electricpower,2013,46(9):145-149.

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