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伊敏褐煤中微量元素的地球化学特征及其无机-有机亲和性分析

, PP. 1173-1183

Keywords: ,腐殖酸,煤大分子结构,微量元素,无机-有机亲和性

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Abstract:

?采用脱矿物质、提取腐殖酸等方法结合icp-ms对伊敏15上、16下煤中的32种微量元素的含量及其赋存特征进行了分析。与地壳克拉克值及中国侏罗-白垩纪煤和世界褐煤中微量元素含量相比,伊敏褐煤中微量元素没有明显富集。脱矿物质处理后,ni明显富集,as略比原煤高,其他微量元素都低于原煤。原煤提取腐殖酸和脱矿物煤提取腐殖酸中ni、mo、cd、sn、w明显富集,这表明ni、mo、cd、sn、w和腐殖酸形成了稳定的有机态化合物。原煤提取腐殖酸残煤和脱矿物煤提取腐殖酸残煤中v、ni、as富集,表明v、ni、as与煤的大分子结构形成了稳定的有机态化合物。根据微量元素和灰分的相关性系数,把微量元素分为以下几类:无机富集元素cr、u;亲无机元素cu、cd、in、sn、ga、y、zr、hf、bi、th;偏无机元素be、sc、rb、sr、nb、cs、ta、pb;偏有机元素v、as、tl、ba、se;亲有机元素li、co、w;有机富集元素ni、zn、mo、sb。

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