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含能材料  2009 

氧化氰二聚环化:对称氧化呋咱衍生物制备的重要途径

DOI: 10.3969/j.issn.1006-9941.2009.06.022

Keywords: 有机化学,氧化呋咱衍生物,二聚反应,氧化氰

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Abstract:

分析了国内外构筑氧化呋咱环的几种常用方法。总结了氧化氰结构的制备方法及其优缺点,如羟肟酰氯与弱碱的作用、醛肟与氧化氮作用、肼钾盐与氧化剂作用等,以及由氧化氰二聚反应获得的具有不同对称结构的氧化呋咱衍生物。列举了部分对称氧化呋咱衍生物的性能,分析结果有望设计和合成性能良好的新氧化呋咱衍生物。

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