CdI2与TSC加成物的合成及结构

CdI2与TSC在丙酮溶剂及水中形成加成物CdI2(C4H10N3S)2？H2O,晶体属单斜晶系,空间群为P21/m.晶胞参数为a=0.7533(3)nm,b=1.535(2)nm,c=0.8437(2)nm,β=90.91(3)°,v=0.976(1)nm3,Mr=648.64,Z=2,Dc=2.20g？cm-3,μ(CuKα)=44.58cm-1,F(000)=608,T=297K.用1622个I≥3σ(I)独立衍射精修结构,最终偏差因子R=0.057,晶体中存在分离的单核络合物CdI2(C4H10N