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反应烧结制备多孔β-sialon/Si_3N_4陶瓷

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Abstract:

以Si粉和Al2O3空心球为原料,采用反应烧结后高温烧结法制备了多孔β-sialon/Si3N4陶瓷。X射线衍射结果表明在0.25MPa的氮气压力下于1300℃反应烧结2h后在0.25MPa的氮气压力下1700℃及1750℃高温烧结2h,制备的样品的组成为β-sialon(Si6-zAlzOzN8-z,z=3)及β-Si3N4,随着烧结温度由1700℃升高至1750℃,β-sialon的相对质量分数由29.9%增加至56.8%。场发射扫描电镜观察结果表明1750℃高温烧结样品的显微结构由大孔β-sialon及疏松的β-Si3N4基体组成。1750℃高温烧结后,样品的气孔率为28%,抗弯强度为92.5MPa。

References

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