全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

高碱含量水泥净浆的显微结构特征及碳化速率

DOI: 10.7521/j.issn.0454-5648.2014.08.08

Full-Text   Cite this paper   Add to My Lib

Abstract:

将硬化后的水泥净浆分别浸泡在NaOH饱和溶液和水中,干燥后测定孔结构参数和碳化速率,评价孔结构特征相近时高碱含量对水泥净浆碳化速率的影响。结果表明水灰比为0.3、0.4及0.5时,硬化水泥净浆孔结构特征相近时,碱含量越高,碳化速率越慢;NaOH溶液浸泡后的水泥净浆,孔结构和密实度均与同条件水中浸泡过的水泥净浆相近,水泥净浆内尚未出现氢氧化钠碳化后可能出现的碳酸钠晶体,未对水泥石孔结构产生影响。碳化由表向里进行过程中,水泥净浆的碳化区易出现微裂缝并延伸到试件内部,致使水泥净浆的各部位碳化深度不均匀,说明使用酚酞溶液的呈色反应评价水泥混凝土的碳化程度时应结合X射线电子计算机断层扫描和X射线衍射技术。明确了碳化不仅可以降低混凝土的pH值,而且由于碳化区易于出现裂缝使钢筋表面暴露于空气中,增加了钢筋腐蚀的概率。

References

[1]   ZITROU E, NIGOLAOU J, TSAKIRIDIS P E. Atmospheric corrosion of steel reinforcing bars produced by various manufacturing process[J]. Constr Build Mater, 2007, 21 (6):1161-1169.
[2]   李翰承.腐食劣化した鉄筋??????構造物の耐力性能評価および補強に関する研究 [D].東京大学博士学位論文,1997:78-89.
[3]   ERDOGAN S T, NIE X, STUTZMAN P E, et al. Micrometer-scale 3-D shape characterization of eight cements: Particle shape and cement chemistry, and the effect of particle shape on laser diffraction particle size measurement [J]. Cem Concr Res, 2010, 40(5):731-739.
[4]   MORGAN I L, ELLINGER H, KLINKSIEK R, et al. Examination of concrete by computerized tomography [J]. J Am Concr Inst, 1980, (1-2):23-27.
[5]   MARTZ H E, SCHNEBECK D J, ROBERSON G P, et al. Computerized tomography analysis of reinforced concrete [J]. ACI Mater, 1993, 90(3):259-264.
[6]   SHAH S P, CHOI S. Nondestructive techniques for studying fracture processes in concrete [J]. Int J Fract, 1999, 98(3-4):351-359.
[7]   ROUGELOT T, BURLION N, BERNARD D, et al. About microcracking dueto leaching in cementitious composites: X-ray microtomography description and numerical approach [J]. Cem Concr Res, 2010, 40(2):271-283.
[8]   MARQUES P F, CHASTRE C. Carbonation service life modelling of RC structures for concrete with Portland and blended cements [J]. Cem Concr Comp, 2013, 37(6):171-184.
[9]   MARQUES P F, COSTA A. Service life of RC structures: carbonation induced corrosion [J]. Constr Build Mater, 2010, 24(3):258-265.
[10]   AQUE M N, KAWAMURA M. Carbonation and chloride-induced corrosion of reinforcement in fly ash concretes [J]. ACI Mater J, 1992, 89(6): 602-605.
[11]   宋晓冰,孔启明,刘西拉.普通硅酸盐混凝土中临界氯离子浓度的试验研究 [J].土木工程学报,2007, 40(11):59-63.
[12]  SONG Xiaobing, KONG Qiming, LIU Xila. China Civ Eng J (in Chinese), 2007, 40(11):59-63.
[13]   柳俊哲,邢锋,贺智敏,等.钢筋混凝土中亚硝酸根与氯离子的临界摩尔比 [J].硅酸盐学报,2010, 38(4):615-620.
[14]  LIU Junzhe, XING Feng, HE Zhimin, et al. J Chin Ceram Soc, 2004, 32 (7):854-857.
[15]   SONG H W, LEE C H, ANN K Y. Factors influencing chloride transport in concrete structures exposed to marine environments [J]. Cem Concr Comp, 2008, 30(2):113-121.
[16]   CASTELLOTE M, ANDRADE C, TURRILLAS X, et al. Accelerated carbonation of cement pastes in situ monitored by neutron diffraction [J]. Cem Concr Res, 2008, 38(2):1365-1373.
[17]   YANG T, KELLER B, MAGYARI E. Direct observation of the carbonation process on the surface of calcium hydroxide crystals in hardened cement paste using an atomic force microscope [J]. J Mater Sci, 2003, 38:1909-1916.
[18]   SURYAVANSHI A K, SWAMY R N. Stability of Friedel’s salt in carbonated concrete structural elements [J]. Cem Concr Res, 1996, 26(5):729-741.
[19]   KWON S J, SONG H W. Analysis of carbonation behavior in concrete using neural network algorithm and carbonation modeling [J]. Cem Concr Res, 2010, 40(1):119-127.
[20]   VERBECKG.CarbonationofhydratedPortlandcement [M].PCABull, 1958, 87:17-36.
[21]   SONG H W, KWON S J. Permeability characteristics of carbonated concrete considering capillary pore structure [J]. Cem Concr Res, 2007, 37(6):909-915.
[22]   ABATEE C, SCHEETZ B E. Aqueous phase equilibria in the system CaO-Al2O3-CaCl2-H2O: The significance and stability of Friedel’s salt [J]. J Am? Ceram Soc, 1995, 78(4):939-944.
[23]   HAN Jiande, PAN Ganghua, SUN Wei. Investigation on carbonation induced mesodefects changes of cement mortar using 3D X-Ray computed tomography [J]. J Chin Ceram Soc, 2011, 399(10):75-79.
[24]   NEPOMUCENOA A. Steel protection capacity of polymeric based cement mortars against chloride and carbonation attacks studied using electrochemical polarization resistance[J]. Cem Concr Comp, 2006, 28(8):716-721.
[25]   NGALA V T, PAGE C L. Effects of carbonation on pore structure and diffusion properties of hydrated cement paste [J]. Cem Concr Res, 1997, 27(7):995-1007.
[26]   BEYENEL M, SNYDER A, LEE R J, et al. Alkali silica reaction as a root cause of distress in a concrete made from alkali carbonate reaction potentially susceptible aggregates [J]. Cem Concr Res, 2013, 51(4):85-95.
[27]   OWSIAK Z. Alkali aggregate reaction in concrete containing high-alkali cement and granite aggregate [J]. Cem Concr Res, 2004, 34(2):7-11.
[28]   PIGNATELLI R, COMI C, MONTEIRO P J M. A coupled mechanical and chemical damage model for concrete affected by alkali silica reaction[J]. Cem Concr Res, 2013, 53(11):196-210.
[29]   LIU Junzhe, LI Yushun, LV Lihua. Effect of anti-freezing admixtures on alkali-silica reaction in mortars[J]. J Wuhan Univ Technol Mater Sci Ed, 2005, 20(2):80-82.
[30]   DUNANTA C F, SCRIVENER K L. Effects of aggregate size on alkali silica reaction induced expansion [J]. Cem Concr Res, 2012, 42(6):745-751.
[31]   SHAYAN A. Effects of seawater on AAR expansion of concrete [J]. Cem Concr Res, 2010, 40(4):563-568.
[32]   GALLUCCI E, SCRIVENER K, GROSO A, et al. 3D experimental investigation of the microstructure of the cement pastes using synchrotron X-ray micro tomography (μCT) [J]. Cem Concr Res, 2007, 37(3):360-368.
[33]   CHOTARD T J, MARTEL M P B, SMITH A. Application of X-ray computed tomography to characterise the early hydration of calcium aluminate cement [J]. Cem Concr Compos, 2003, 25(1):145-152.
[34]   BENTZ D P, MIZELL S, SATTERFIELD S, et al. The visible cement data set [J]. J Res Natl Inst Stand Technol, 2002, 107(2):137-148.
[35]   BURLION N, BERNARD D, CHEN D. X-ray microtomography: Application to microstructure analysis of a cementitious material during leaching process [J]. Cem Concr Res, 2006, 36(2):346-357.
[36]   SUGIYAMA T, PROMENTILLA M A B, HITOMI T, et al. Application of synchrotron micro tomography for pore structure characterization of deteriorated cementitious materials due to leaching[J]. Cem Concr Res, 2010, 40(8):1265-1270.
[37]   STOCK S R, NAIK N K, WILKINSON A P, et al. X-ray micro tomography(micro CT) of the progression of sulfate attack of cement paste[J]. Cem Concr Res, 2002, 32(10):1673-1675.
[38]   PROMENTILLA M A B, SUGIYAMA T, HITOMI T, et al. Quantification of tortuosity in hardened cement pastes using synchrotron-based X-ray computed microtomography [J]. Cem Concr Res, 2009, 39(6):548-557.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133