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均相沉淀–燃烧法合成单分散球形SiO2/CaMoO4:Eu3+,Li+红色荧光粉的发光性能

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Abstract:

采用均相沉淀和燃烧合成相结合的方法合成了单分散球形核壳结构SiO2/CaMoO4Eu3+,Li+荧光粉。用X射线衍射仪、扫描电子显微镜、透射电子显微镜和荧光光谱对样品的物相、结构、显微形貌和发光性能进行了表征。结果表明产品物相由四方晶系CaMoO4和非晶态SiO2组成;CaMoO4Eu3+,Li+荧光粉微粒在球形SiO2表面结晶良好,所形成的核壳结构微球粒径均匀;该荧光粉能在近紫外光(395nm)激发下,发出波长为617nm的红光。

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