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固溶体CdxMn1–xS光催化剂的制备及光解水制氢

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Abstract:

为了开发具有可见光响应的高活性光解水制氢催化剂,采用水热合成法制备了CdxMn1–xS固溶体光催化剂,通过X射线衍射、紫外–可见吸收光谱测试手段对所制备催化剂进行了表征。结果表明CdxMn1–xS固溶体具有和CdS相似的结构,即六方相纤维锌矿结构,并且CdxMn1–xS固溶体在可见光下有很强的吸收,Cd0.34Mn0.66S,Cd0.48Mn0.52S及Cd0.68Mn0.32S的禁带宽度分别为2.17、2.25和2.32eV。光催化分解水制氢实验表明催化剂制氢活性由大到小的顺序排列为Cd0.48Mn0.52S,Cd0.34Mn0.66S,Cd0.68Mn0.32S,CdS,MnS。Cd0.48Mn0.52S产氢速率可达273.3μmol/h。

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