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化工进展  2015 

深部煤层封存CO2过程中的煤基质溶胀效应

DOI: 10.16085/j.issn.1000-6613.2015.07.037

Keywords: 煤层,存埋,二氧化碳,煤基质,溶胀

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Abstract:

强化煤层气甲烷(CH4)采收率的深部煤层封存二氧化碳(CO2)技术能够将主要人为温室气体(CO2)进行有效的地质存储。考虑到CO2流体和煤体的自身特性,封存过程中的CO2流体将会诱导煤基质发生溶胀效应。溶胀效应将会对煤层封存CO2技术构成潜在的影响。为此,本文结合国内外相关研究工作,归纳了流体诱导煤基质溶胀的规律,指出了煤基质溶胀对煤层封存CO2过程的影响,介绍了流体诱导煤基质溶胀的分析手段,提出了封存过程中煤基质溶胀的研究趋势。分析表明①煤基质溶胀程度与流体种类、压力、温度和煤的变质程度有关;②CO2诱导煤基质溶胀效应将会降低煤层的渗透性能,进而影响CO2等流体在煤层内部的有效运移;③溶胀效应会影响煤层的CO2封存性能,建立涉及溶胀效应的煤吸附理论模型是溶胀效应研究的重要课题;④煤基质溶胀机理及其可逆性能研究目前存在争议,研究人员需要从煤体理化结构的研究出发以明确上述问题。

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