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化工进展  2015 

刺激响应性聚合物的设计、合成及其应用研究新进展

DOI: 10.16085/j.issn.1000-6613.2015.08.027

Keywords: 刺激响应性,设计与合成,聚合物,聚合,水溶液

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Abstract:

介绍了研究刺激响应性聚合物的意义,针对水体系中的刺激响应性聚合物,介绍了近年来刺激响应性聚合物的设计与合成中的应用研究新进展,主要从3个方面进行阐述①单一刺激响应性聚合物,包括温度、pH值、光、其他刺激响应性聚合物;②双重刺激响应性聚合物,包括温度-pH值、温度-光、温度-氧化还原刺激响应聚合物、pH值-氧化还原刺激响应聚合物;③多重刺激响应性聚合物,包括温度-光-pH值、温度-光-氧化还原、温度-pH值-CO2刺激响应聚合物。着重评述了水体系中双重和多重刺激响应性聚合物的合成研究及应用。最后总结了多重刺激响应性聚合物应用研究的现状及问题,指出开发刺激响应性高度可控、灵敏度高、可逆性好的新型多重刺激响应性聚合物是未来的研究方向。

References

[1]  Ma X, Tian H. Stimuli-responsive supramolecular polymers in aqueous solution[J]. Accounts of Chemical Research, 2014, 47: 1971-1981.
[2]  李雪梅, 贺继东. 两亲性聚合物分子自组装的研究进展[J]. 化工进展, 2014, 33(10): 2665-2699. 浏览
[3]  Liu J, Detrembleur C, Hurtgen M, et al. Thermo-responsive gold/poly(vinyl alcohol)-b-poly(N-vinylcaprolactam) core-corona nanoparticles as a drug delivery system[J]. Polymer Chemistry, 2014, 5: 5289-5299.
[4]  Schattling P, Jochum D F, Theato P. Multi-responsive copolymers: Using thermo-, light-and redox stimuli as three independent inputs towards polymeric information processing[J]. Chemical Communications, 2011, 47: 8859-8861.
[5]  Li G Y, Guo L, Wen Q W, et al. Thermo-and pH-sensitive ionic-crosslinked hollow spheres from chitosan-based graft copolymer for 5-fluorouracil release[J]. International Journal of Biological Macromolecules, 2013, 55: 69-74.
[6]  Lu Y, Sun W J, Gu Z. Stimuli-responsive nanomaterials for therapeutic protein delivery[J]. Journal of Controlled Release, 2014, 194: 1-19.
[7]  Islam R M, Gao Y F, Li X, et al. Stimuli-responsive polymeric materials for human health applications[J]. Chinese Science Bulletin, 2014, 59(32): 4237-4255.
[8]  Hu J M, Liu S Y. Engineering responsive polymer building blocks with Host-Guest molecular recognition for functional applications[J]. Accounts of Chemical Research, 2014, 47: 2084-2095.
[9]  Wu X W, Chen X F, Guan H Y, et al. A recyclable thermo-responsive catalytic system based on poly(N-isopropylacrylamide)-coated POM@SBA-15 nanospheres[J]. Catalysis Communications, 2014, 51: 29-32.
[10]  Xue B L, Gao L C, Hou Y P, et al. Temperature controlled water/oil wettability of a surface fabricated by a block copolymer: Application as a dual water/oil on-off switch[J]. Advanced Materials, 2013, 25: 273-277.
[11]  Schild G H. Poly(N-isopropylacrylamide): Experiment, theory and application[J]. Progress in Polymer Science, 1992, 17: 163-249.
[12]  Nakayama M, Okano T. Polymer terminal group effects on properties of thermoresponsive polymeric micelles with controlled outer-shell chain lengths[J]. Biomacromolecules, 2005, 6: 2320-2327.
[13]  Chen G H, Haffman S A. Graft copolymers that exhibit temperature-induced phase transitions over a wide range of pH[J]. Nature, 2014, 5: 2961-2972.
[14]  Li Q L, Gao C Q, Li S T, et al. Doubly thermo-responsive ABC triblock copolymer nanoparticles prepared through dispersion RAFT Polymerization[J]. Polymer Chemistry, 2014, 5: 2961-2972.
[15]  Zhou C, Qian S S, Li X J, et al. Synthesis and characterization of well-defined PAA-PEG multi-responsive hydrogels by ATRP and click chemistry[J]. Royal Society of Chemistry Advances, 2014, 4: 54631-54640.
[16]  Abdellaoui-Arous N, Djadoun S. Poly[2-(N,N-dimethylamino) ethyl methacrylate]/poly(styrene-co-methacrylic acid) interpolymer complexes[J]. Macromolecular Symposium, 2011, 303: 123-133.
[17]  Liu R, Liao P H, Liu J K, et al. Responsive polymer-coated mesoporous silica as a pH-sensitive nanocarrier for controlled release[J]. Langmuir, 2011, 27: 3095-3099.
[18]  Schumers J M, Fustin C A, Gohy J F. Light-responsive block copolymers[J]. Macromolecular Rapid Communications, 2010, 31: 1588-1607.
[19]  Son S, Shin E, Kim B-S. Light-responsive micelles of spiropyran initiated hyperbranched polyglycerol for smart drug delivery[J]. Biomacromolecules, 2014, 15: 628-634.
[20]  Zhao H, Sterner S E, Coughlin B E, et al. o-Nitrobenzyl alcohol derivatives: Opportunities in polymer and materials science[J]. Macromolecules, 2012, 45, 1723-1736.
[21]  Schumers J M, Bertrand O, Fustin C A, et al. Synthesis and self-assembly of diblock copolymers bearing 2-nitrobenzyl photocleavable side groups[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2012, 50: 599-608.
[22]  Theato P. One is enough: Influencing polymer properties with a single chromophoric unit[J]. Angewandte Chemie International Edition, 2011, 50: 5804-5806.
[23]  Bapat P A, Ray G J, Savin A D, et al. Redox-responsive dynamic-covalent assemblies: Stars and miktoarm stars[J]. Macromolecules, 2013, 46: 2188-2198.
[24]  Oyaizu K, Nishide H. Radical polymers for organic electronic devices: A radical departure from conjugated polymers[J]. Advanced Materials, 2009, 21: 2339-2344.
[25]  Egawa Y, Miki R, Seki T. Colorimetric sugar sensing using boronic acid-substituted azobenzenes[J]. Materials, 2014, 7: 1201-1220.
[26]  Vancoillie G, Pelz S, Holder E, et al. Direct nitroxide mediated (co)polymerization of 4-vinylphenylboronic acid as route towards sugar sensors[J]. Polymer Chemistry, 2012, 3: 1726-1729.
[27]  Yan Q, Zhou R, Fu C K, et al. CO2-responsive polymeric vesicles that breathe[J]. Angewandte Chemie International Edition, 2011, 50: 4923-4927.
[28]  Han D, Boissiere O, Kumar S, et al. Two-way CO2-switchable triblock copolymer hydrogels[J]. Macromolecules, 2012, 45: 7440-7445.
[29]  Chen P Y, Chen J Y, Cao Y. Self-assembly behavior of thermo-and pH-responsive diblock copolymer of poly(N-isopropylacrylamide)-block-poly(acrylic acid) synthesized via reversible addition-fragmentation chain transfer polymerization[J]. Journal of Macromolecular Science Pure and Applied Chemistry, 2013, 50: 478-486.
[30]  Jiang X Y, Lu G L, Feng C, et al. Poly(acrylic acid)-graft-poly(N-vinylcaprolactam): A novel pH and thermo dual-stimuli responsive system[J]. Polymer Chemistry, 2013, 4: 3876-3884.
[31]  Bütün V, Armes P S, Billingham C N. Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers[J]. Polymer, 2001, 42: 5993-6008.
[32]  Zhao Y, Shi X B, Gao H Y, et al. Thermo-and pH-sensitive polyethylene-based diblock and triblock copolymers: Synthesis and self-assembly in aqueous solution[J]. Journal of Materials Chemistry, 2012, 22: 5737-5745.
[33]  Kungwatchakun D, Irie M. Photoresponsive polymers: Photocontrol of the phase separation temperature of aqueous solutions of poly-[N-isopropylacrylamide-co-N-(4-phenylazophenyl) acrylamide][J]. Makromolekulare Chemie, Rapid Communications, 1988, 9: 243-246.
[34]  Akiyama H, Tamaoki N. Polymers derived from N-isopropylacrylamide and azobenzene-containing acrylamides: Photoresponsive affinity to water[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2004, 42: 5200-5214.
[35]  Blasco E, Schmidt V K J B, Barner-Kowollik C, et al. Dual thermo-and photo-responsive micelles based on miktoarm star polymers[J]. Polymer Chemistry, 2013, 4: 4506-4514.
[36]  Kuramoto N, Shishido Y, Nagai K. Thermosensitive and redox-active polymers: Preparation and properties of poly(N-ethylacrylamide-co-vinylferrocene) and poly(N,N-diethylacrylamide-co-vinylferrocene) [J]. Journal of Polymer Science Part A: Polymer Chemistry, 1997, 35: 967-1972.
[37]  Schmidt V K J B, Elbert J, Barner-Kowollik C, et al. Individually addressable thermo-and redox-responsive block copolymers by combining anionic polymerization and RAFT protocols[J]. Macromolecular Rapid Communications, 2014, 35: 708-714.
[38]  Phillips J D, Gibson I M. Degradable thermoresponsive polymers which display redox-responsive LCST behaviour[J]. Chemical Communications, 2012, 48: 1054-1056.
[39]  Gyarmati B, Vajna B, Némethy á, et al. Redox-and pH-responsive cysteamine-modified poly(aspartic acid) showing a reversible Sol-Gel transition[J]. Macromolecular Bioscience, 2013, 13: 633-640.
[40]  Wang L, Li Y K, Xu Y Q, et al. A facile construction method for pH and oxidation dual-responsive assembly based on ferrocene-modified chitooligosaccharide[J]. Reactive and Functional Polymers, 2014, 76: 1-7.
[41]  Ding J X, Xiao C S, Yan L S, et al. pH and dual redox responsive nanogel based on poly(l-glutamic acid) as potential intracellular drug carrier[J]. Journal of Controlled Release, 2011, 152: e1-e132.
[42]  Tang X D, Liang X C, Gao L C, et al. Water-soluble triply-responsive homopolymers of N,N-dimethylaminoethyl methacrylate with a terminal azobenzene moiety[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2010, 48: 2564-2570.
[43]  Achilleos S D, Vamvakaki M. Multiresponsive spiropyran-based copolymers synthesized by atom transfer radical polymerization[J]. Macromolecules, 2010, 43: 7073-7081.
[44]  Sumaru K, Kameda M, Kanamori T, et al. Characteristic phase transition of aqueous solution of poly(N-isopropylacrylamide) functionalized with spirobenzopyran[J]. Macromolecules, 2004, 37: 4949-4955.
[45]  Zhang J, Liu H J, Yuan Y, et al. Thermo-, pH-, and light-responsive supramolecular complexes based on a thermoresponsive hyperbranched polymer[J]. American Chemical Society Macro Letters, 2013, 2: 67-71.
[46]  Dong J, Wang Y N, Zhang J, et al. Multiple stimuli-responsive polymeric micelles for controlled release[J]. Soft Matter, 2013, 9: 370-373.
[47]  Wu H, Dong J, Li C C, et al. Multi-responsive nitrobenzene-based amphiphilic random copolymer assemblies[J]. Chemical Communications, 2013, 49: 3516-3518.
[48]  Yuan W Z, Guo W, Zou H, et al. Tunable thermo-, pH-and light-responsive copolymer micelles[J]. Polymer Chemistry, 2013, 4: 3934-3937.
[49]  Alvarez-Rodríguez R, Arias J F, Santos M, et al. Gold tailored photosensitive elastin-like polymer: Synthesis of temperature, pH and UV-vis sensitive probes[J]. Macromolecular Rapid Communications, 2010, 31: 568-573.
[50]  Schattling P, Jochum D F, Theato P. Multi-responsive copolymers: Using thermo-, light-and redox stimuli as three independent inputs towards polymeric information processing[J]. Chemical Communications, 2011, 47: 8859-8861.
[51]  Huang X G, Jiang X L, Yang Q Z, et al. Triple-stimuli (pH/thermo/reduction) sensitive copolymers for intracellular drug delivery[J]. Journal of Materials Chemistry B, 2013, 1: 1860-1868.
[52]  Jiang X, Feng C, Lu G L, et al. Thermoresponsive homopolymer tunable by pH and CO2[J]. American Chemical Society Macro Letters, 2014, 3: 1121-1125.

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