|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
电子束辐射聚合制备槲皮素-镍(Ⅱ)金属配位分子印迹聚合物及其识别性能研究
DOI: 10.3724/SP.J.1105.2013.12272, PP. 526-533
Keywords: 电子束辐射聚合,辐射剂量,金属配位,分子印迹聚合物,槲皮素-镍(Ⅱ)
Abstract:
以电子束为辐照射线源,采用辐射聚合法成功制备了槲皮素-Ni(Ⅱ)金属配位分子印迹聚合物.通过紫外光谱研究了槲皮素与Ni(Ⅱ)之间的配位结构、配位作用方式及配位比,并按照1∶2的比例形成稳定配合物,同时也验证了槲皮素、Ni(Ⅱ)及功能单体甲基丙烯酸三者发生了金属配位印迹作用.利用红外光谱对产物的结构进行了表征.透射电镜、扫描电镜、吸附动力学实验分别考察辐射剂量对聚合物的微观形貌、吸附动力学性能的影响,结果表明辐射剂量对印迹聚合物的吸附性能有显著影响.同时选择性吸附实验结果显示该印迹聚合物对槲皮素-Ni(Ⅱ)配合物表现出明显的吸附选择性和特异性,最大结合量可达82.22μmol/g.对黄芩素和柚皮素的吸附选择性较差,分离因子分别为3.915和5.443.
| [1] | 1 Alexander C,Andersson H S,Andersson L I,Ansell R J,Kirsch N,Nicholls I A,O’Mahony J,Whitcombe M J.J Mol Recogni,2006,19(2):106~180
|
| [2] | 2 Shi H Q,Tsai W B,Garrison M D,Ferrafi S,Rather B D.Nature,1999,398:593~597
|
| [3] | 3 Peter A G,Amaia Z E.J Chromatogr B,2004,804:173~182
|
| [4] | 4 Apodaca D C,Pernites R B,Ponnapati R,Del Mundo F R,Advincula R C.Macromolecules,2011,44(17):6669~6682
|
| [5] | 5 Gupta R,Kumar A.J Sol-Gel Sci Tech,2011,58(1):182~194
|
| [6] | 6 Li Ping(李萍),Rong Fei(戎非),Zhu Xinle(朱馨乐),Hu Xunzhe(胡濬喆),Yuan Chunwei(袁春伟).Acta Polymerica Sinica (高分子学报),2003,(5):724~727
|
| [7] | 7 Li Ding(李丁),Gao Baojiao(高保娇),Xu Wenmei(许文梅).Acta Chimica Sinica(化学学报),2011,69(24):3019~3027
|
| [8] | 15 Zhou Jie(周杰),He Xiwen(何锡文),Shi Huiming(史慧明).Journal of Analytical Science(分析科学学报),1999,15(2):89~93
|
| [9] | 16 Zheng Ning(郑宁),Li Yuanzong(李元宗),Wang Zongmu(王宗睦).Acta Chimica Sinica(化学学报),2001,59(10):1572~1576
|
| [10] | 17 Shan Juanjuan(单娟娟),Wang Bing(王兵).Acta Polymerica Sinica(高分子学报),2011(1):100~106
|
| [11] | 18 Yao Xinsheng(姚新生),Wu Lijun(吴立军),Wu Jizhou(吴继洲).The Medicinal Chemistry of Natural Products(天然药物化学),Beijing (北京):People’s Mdeical Publishing House(人民卫生出版社),2004.177~18
|
| [12] | 8 S un Yan(孙妍),Wang Bing(王兵).Chemical Journal of Chinese Universities(高等学校化学学报),2012,33(04):838~842
|
| [13] | 9 Reimhult K,Yoshimatsu K,Risveden K,Chen S,Ye L,Krozer A.Biosens Bioelectron,2008,23(12):1908~1914
|
| [14] | 10 Jiang T H,Zhao L X,Chu B L,Feng Q H,Yan W,Lin J M.Talanta,2009,78(2):442~447
|
| [15] | 11 Skottrup P D,Nicolaisen M,Justesen A F.Biosens Bioelectron,2008,24(3):339~2348
|
| [16] | 12 Chen Z Y,Hua Z D,Wang J,Guan Y,Zhao M P,Li Y Z.Appl Catal A-Gen,2007,328(2):252~258
|
| [17] | 13 Wu Y F,Zhuang Y F,Liu S Q,He L.Anal Chim Acta,2008,630(2):186~193
|
| [18] | 14 Wu Zhihong(吴志宏),Jiang Bo(蒋波),Zhang Xingdong(张兴栋).Materials Review(材料导报),2005,19 (2):27~30
|
| [19] | 19 Gautam L,Scott K S,Cole M D.J Anal Toxicol, 2005,29(5):339~344
|
| [20] | 20 Hawkins D M,Trache A,Stevenson D,Holzenburg A,Meininger G,Reddy S M.Biomacromolecules,2006,7(9):2560~2564
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
