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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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高透明高韧性黏土/聚乙烯醇人造贝壳
DOI: 10.11777/j.issn1000-3304.2015.14390, PP. 363-368
Keywords: 黏土,层状结构,力学性能,贝壳,自组装
Abstract:
天然贝壳由碳酸钙片和少量生物聚合物组成,同时具有高的强度和韧性.这些优异的力学性能主要归因于高的碳酸钙片含量、精心设计的层状结构、强的界面粘结和碳酸钙片适当的长径比,使得贝壳以片拔出的形式断裂,导致优异的强度和韧性.受天然贝壳结构和力学性能之间关系的启发,采用蒸发诱导自组装方法制备了黏土/聚乙烯醇人造贝壳,其中黏土的含量为52wt%.扫描电镜、透射电镜和X射线衍射证实了其层状结构.红外光谱证实黏土和聚乙烯醇之间形成氢键.拉伸测试测得人造贝壳强度为(90.2±8.0)MPa,与天然贝壳(80~135MPa)相当;人造贝壳断裂应变高达(14.7±2.3)%,远高于天然贝壳(约2%);人造贝壳拉伸韧性高达(10.6±3.0)MJ/m3.此外,所制备的人造贝壳透明,透明度高达90%以上.
| [1] | 12 Yao H B,Tan Z H,Fang H Y,Yu S H.Angew Chem Int Ed,2010,49(52):10127~10131
|
| [2] | 13 Yao H B,Mao L B,Yan Y X,Cong H P,Lei X,Yu S H.ACS Nano,2012,6(9):8250~8260
|
| [3] | 14 Wang X,Bai H,Yao Z,Liu A,Shi G.J Mater Chem,2010,20(41):9032~9036
|
| [4] | 15 Laaksonen P,Walther A,Malho J M,Kainlauri M,Ikkala O,Linder M B.Angew Chem Int Ed,2011,50(37):8688~8691
|
| [5] | 16 Cheng Q,Wu M,Li M,Jiang L,Tang Z.Angew Chem Int Ed,2013,52(13):3750~3755
|
| [6] | 17 Hu X,Xu Z,Gao C.Sci Rep,2012,2:767
|
| [7] | 19 Liu Z,Xu Z,Hu X Z,Gao C.Macromoleculs,2013,46(17):6931~6941
|
| [8] | 20 Zhao Xiaoli(赵晓丽),Gao Chao(高超).Acta Polymerica Sinica(高分子学报),2014,(10):1301~1313
|
| [9] | 21 Hu X,Xu Z,Liu Z,Gao C.Sci Rep,2013,3:2374
|
| [10] | 22 Wang J,Cheng Q,Lin L,Chen L,Jiang L.Nanoscale,2013,5(14):6356~6362
|
| [11] | 23 Wang J,Cheng Q,Lin L,Jiang L.ACS Nano,2014,8(3):2739~2745
|
| [12] | 24 Wang Y,Yu J,Chen L,Hu Z,Shi Z,Zhu J.RSC Adv,2013,3(43):20353~20362
|
| [13] | 25 Huang L,Li C,Yuan W J,Shi G Q.Nanoscale,2013,5(9):3780~3786
|
| [14] | 26 Barthelat F,Tang H.Zavattieri P D,Li C M,Espinosa H D.J Mech Phys Solids,2007,55(2):306~337
|
| [15] | 27 Podsiadlo P,Kaushik A K,Shim B S,Agarwal A,Tang Z,Waas A M,Arruda E M,Kotov N A.J Phys Chem B,2008,112(46):14359~14363
|
| [16] | 28 Vertlib V,Dietike M,Spolenak R,Puzrin A M.J Mater Res,2008,23(4):1026~1035
|
| [17] | 29 Han J,Dou Y,Yan D,Ma J,Wei M,Evans D G,Duan X.Chem Commun,2011,47(18):5274~5276
|
| [18] | 30 Wang R Z,Suo Z,Evans A G,Yao N,Aksay I A.J Mater Res,2001,16(9):2485~2493
|
| [19] | 31 Bonderer L J,Studart A R,Gauckler L J.Science,2008,319(5866):1069~1073
|
| [20] | 32 Sato H,Yamagishi A,Kawamura K.J Phys Chem B,2001,105(33):7990~7997
|
| [21] | 33 Yano H,Sugiyama J,Nakagaito A N,Nogi M,Matsuura T,Hikita M,Handa K.Adv Mater,2005,17(2):153~155u J.RSC Adv, 2013, 3(43):20353~20362
|
| [22] | 25 Huang L, Li C, Yuan W J, Shi G Q.Nanoscale, 2013, 5(9):3780~3786
|
| [23] | 26 Barthelat F, Tang H.Zavattieri P D, Li C M, Espinosa H D.J Mech Phys Solids, 2007, 55(2):306~337
|
| [24] | 1 Espinosa H D, Rim J E,Barthelat F,Buehler M J.Prog Mater Sci,2009,54(8):1059~1100
|
| [25] | 2 Jackson A,Vincent J,Turner R.Proc Royal Soc London Ser B,1988,234(1277):415~440
|
| [26] | 3 Wang J,Cheng Q,Tang Z.Chem Soc Rev,2012,41(3):1111~1129
|
| [27] | 4 Yao H B,Ge J,Mao L B,Yan Y X,Yu S H.Adv Mater,2014,26(1):163~188
|
| [28] | 5 Cheng Q,Jiang L,Tang Z.Acc Chem Res,2014,47(4):1256~1266
|
| [29] | 6 Lu H,Chen Z,Ma C.J Mater Chem,2012,22(32):16182~16190
|
| [30] | 7 Yu,Xiaowen(于小雯),Shi,Gaoquan(石高全).Acta Polymerica Sinica(高分子学报),2014,(7):885~895
|
| [31] | 8 Tang Z,Kotov N A,Magonov S,Ozturk B.Nat Mater,2003,2(6):413~418
|
| [32] | 9 Podsiadlo P,Liu Z,Paterson D,Messersmith P B,Kotov N A.Adv Mater,2007,19(7):949~955
|
| [33] | 10 Podsiadlo P,Kaushik A K,Arruda E M,Waas A M,Shim B S,Xu J,Nandivada H,Pumplin B G,Lahann J,Ramamoorthy A,Kotov N A.Science,2007,318(5847):80~83
|
| [34] | 11 Walther A,Bjurhager I,Malho J M,Pere J,Ruokolainen J,Berglund L A,Ikkala O.Nano Lett,2010,10(8):2742~2748
|
| [35] | 18 Zhao X,Xu Z,Zheng B,Gao C.Sci Rep,2013,3:3164
|
| [36] | 27 Podsiadlo P, Kaushik A K, Shim B S, Agarwal A, Tang Z, Waas A M, Arruda E M, Kotov N A.J Phys Chem B, 2008, 112(46):14359~14363
|
| [37] | 28 Vertlib V, Dietike M, Spolenak R, Puzrin A M.J Mater Res, 2008, 23(4):1026~1035
|
| [38] | 29 Han J, Dou Y, Yan D, Ma J, Wei M, Evans D G, Duan X.Chem Commun, 2011, 47(18):5274~5276
|
| [39] | 30 Wang R Z, Suo Z, Evans A G, Yao N, Aksay I A.J Mater Res, 2001, 16(9):2485~2493
|
| [40] | 31 Bonderer L J, Studart A R, Gauckler L J.Science, 2008, 319(5866):1069~1073
|
| [41] | 32 Sato H, Yamagishi A, Kawamura K.J Phys Chem B, 2001, 105(33):7990~7997
|
| [42] | 33 Yano H, Sugiyama J, Nakagaito A N, Nogi M, Matsuura T, Hikita M, Handa K.Adv Mater, 2005, 17(2):153~155 ？
|
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