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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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双核过渡金属络合物引发氮分子活化研究
DOI: 10.7536/PC121211, PP. 1325-1333
Keywords: 过渡金属络合物,固氮,氮分子活化,官能化,CO/CO2协助活化
Abstract:
将自然界资源丰富但化学性质上极其惰性的氮气分子在温和条件下转化为氨及其他含氮化合物,具有非常重要的意义。过渡金属络合物引发氮分子的活化及官能化已成为现代工业固氮的一大研究热点。本文回顾了氮分子与双核过渡金属络合物结合的键型模式,总结了影响氮分子活化的诸多因素如配体调变效应、金属调变效应等,对双核过渡金属络合物引发的双氮裂解、双氮官能化及CO/CO2协助双氮活化官能化等反应的实验与理论研究现状和进展进行了简要综述,并对未来过渡金属络合物在氮分子固定的应用发展作了展望。
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