全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
化学进展  2015 

软质PVC制品中增塑剂迁移带来的问题及应对

DOI: 10.7536/PC140826, PP. 286-296

Keywords: 软质PVC,增塑剂,DEHP,迁移,禁令,争议

Full-Text   Cite this paper   Add to My Lib

Abstract:

聚氯乙烯(PVC)是世界第二大通用塑料,其中软质PVC制品占PVC市场份额的30%,它被广泛用于制造人造皮革、食品包装材料、电线电缆和儿童玩具等。软质PVC中使用的增塑剂主要是邻苯二甲酸二(2-乙基)己酯(DEHP),它具有与PVC相容性良好、增塑效率高、价格低廉、不影响制品的安全性和电绝缘性等诸多优点。但由于DEHP为小分子物质,且与PVC之间并无化学键合,其添加量又通常高达30wt%~50wt%,因此DEHP容易迁移到外部介质中,使制品的性能劣化,同时造成环境污染。在医疗器械和儿童玩具等敏感领域,DEHP的迁移还会危害人体健康。因此,增塑剂迁移所带来的问题引起了人们的广泛关注,亟待解决。本文介绍了DEHP迁移所带来的问题及DEHP目前所面临的使用禁令和争议,全面综述了国内外近年来为解决DEHP迁移所采取的应对措施及获得的研究成果,并对各种措施的优缺点进行了总结,以期进行更深入的研究,找到更为科学和有效的解决方案。

References

[1]  石万聪(Shi W C), 石志博(Shi Z B), 蒋平平(Jiang P P). 增塑剂及其应用(Plasticizer and Its Application). 北京:化学工业出版社(Peking: Chemical Industry Press), 2002. 6.
[2]  Ceresana. Market Study: Polyvinyl Chloride (3rd Edition) UC-9505, (2005-07-30). . http://www.ceresana.com/en/market-studies/plastics/polyvinyl-chloride/
[3]  Chiellini F, Ferri M, Morelli A, Dipaola L, Latini G. Prog.Polym. Sci., 2013, 38(7): 1067.
[4]  Gonzalez N, Fernandez-Berridi M J. J. Appl. Polym. Sci., 2006, 101(3): 1731.
[5]  Audic J, Reyx D, Brosse J. J. Appl. Polym. Sci., 2003, 89(5): 1291.
[6]  Monney L, Jamois-Tasserie M, Dubois C, Lallet P, Villa F,Renaud C. Polym. Degrad. Stabil., 2001, 72(3): 459.
[7]  Jaeger R J, Rubin R J. New Engl. J. Med., 1972, 287(22): 1114.
[8]  Tickner J A, Schettler T, Guidotti T, McCally M, Rossi M.Am. J. Ind. Med., 2001, 39(1): 100.
[9]  Scientific Committee on Emerging and Newly-Identified Health Risks. Opinion on the safety of medical devices containing DEHP plasticized PVC or other plasticizers on neonates and other groups possibly at risk, (2008-02-06). . http://ec.europa.eu/health/archive/ph_risk/committees/04_scenihr/docs/scenihr_o_014.pdf
[10]  Hansen O G. Med. Device. Technol., 2006, 17(3): 16.
[11]  Dalgaard M, Nellemann C, Lam H R, Sorensen I K, Ladefoged O. Toxicol. Lett., 2001, 122(1): 69.
[12]  Gimeno P, Thomas S, Bousquet C, Maggio A, Civade C, Brenier C, Bonnet P. J. Chromatogr. B, 2014, 949: 99.
[13]  Genay S, Luciani C, Decaudin B, Kambia N, Dine T, Azaroual N, Di Martino P, Barthelemy C, Odou P. Int. J. Pharm., 2011, 412(1): 47.
[14]  Biedermann-Brem S, Biedermann M, Pfenninger S, Bauer M, Altkofer W, Rieger K, Hauri U, Droz C, Grob K. Chromatographia, 2008, 68(3/4): 227.
[15]  Brouillet S, Fugit J. Polym. Bull., 2009, 62(6): 843.
[16]  Hakkarainen M. Polym. Degrad. Stabil., 2003, 80(3): 451.
[17]  Ferruti P, Mancin I, Ranucci E, De Felice C, Latini G, Laus M. Biomacromolecules, 2003, 4(1): 181.
[18]  Penco M, Sartore L, Bignotti F, Rossini M, D'Amore A, Fassio F. Macromol. Symp., 2002, 180(1): 9.
[19]  Zhou J, Ritter H. Polym. Int., 2011, 60(8): 1158.
[20]  Lee J H, Kim K O, Ju Y M. J. Biomed. Mater. Res., 1999, 48(3): 328.
[21]  Koleske J V, Lundberg R D. J. Polym. Sci. Pol. Phys., 1969, 7(5): 795.
[22]  Pena J R, Hidalgo M, Mijangos C. J. Appl. Polym. Sci., 2000, 75(10): 1303.
[23]  Sunny M C, Ramesh P, George K E. J. Elastom. Plast., 2004, 36(1): 19.
[24]  Sunny M C, Ramesh P, George K E. J. Appl. Polym. Sci., 2006, 102(5): 4720.
[25]  Choi W, Chung J W, Kwak S Y. ACS Appl. Mater. Inter., 2014, 6(14): 11118.
[26]  戴继湘(Dai J X), 潘春跃(Pan C Y), 喻桂朋(Yu G P). 广州化工(Guangzhou Chemical Industry), 2013, 41(12): 75.
[27]  Yue L, Cao Y, Huang T, Huang L, Bai Y, Zhou Y. Aust. J. Chem., 2014, 67(1): 22.
[28]  Rahman M, Brazel C S. Polym. Degrad. Stabil., 2006, 91(12): 3371.
[29]  Hou L X, Wang S. Polym. Bull., 2011, 67(7): 1273.
[30]  Kuo S W, Chang F C. Prog. Polym. Sci.,2011,36(12): 1649.
[31]  Soong S Y, Cohen R E, Boyce M C. Macromolecules, 2006, 39(8): 2900.
[32]  Soong S Y, Cohen R E, Boyce M C. Polymer, 2007, 48(5): 1410.
[33]  王宏亚(Wang H Y). 山西化工(Shanxi Chemical Industry), 1984, 3: 47.
[34]  Elicegui A, Del Val J J, Bellenger V, Verdu J. Polymer, 1997, 38(7): 1647.
[35]  Navarro R, Bierbrauer K, Mijangos C, Goiti E, Reinecke H. Polym. Degrad. Stabil., 2008, 93(3): 585.
[36]  Navarro R, Perrino M P, Tardajos M G, Reinecke H. Macromolecules, 2010, 43(5): 2377.
[37]  孙华圳(Sun H Z), 杨坡(Yang P), 范浩军(Fan H J), 陈意(Chen Y). 高分子学报(Acta Polymerica Sinica), 2014, 2: 233.
[38]  Earla A, Braslau R. Macromol. Rapid Comm., 2014, 35(6): 666.
[39]  Yu B Y, Chung J W, Kwak S Y. Environ. Sci. Technol., 2008, 42(19): 7522.
[40]  Chung J W, Kim S H, Jung S J, Kwak S. Eur. Polym. J., 2009, 45(8): 2164.
[41]  Sreenivasan K. J. Appl. Polym. Sci., 1996, 59(13): 2089.
[42]  Yu B Y, Lee A R, Kwak S. Eur. Polym. J., 2012, 48(5): 885.
[43]  林卫平(Lin W P), 钱欣(Qian X), 王旭(Wang X). 塑料工业(Plasticizer Industry), 2004, 31(12): 19.
[44]  李树材(Li S C), 左治(Zuo Z). 塑料科技(Plastic Science and Technology), 2006, 34(3): 4.
[45]  Yang B H, Bai Y P, Cao Y J. J. Appl. Polym. Sci., 2010, 115(4): 2178.
[46]  石全英(Shi Q Y), 杜林雪(Du L X), 李喜宏(Li X H), 刘霞罗(Liu X L), 金山(Jin S), 刘海娇(Liu H J). 食品工业科技(Food Industry Science and Technology), 2013, 34(19): 66.
[47]  秦晓洁(Qin X J), 蒋平平(Jiang P P), 李志莹(Li Z Y), 冷炎(Ling Y), 张萍波(Zhang P B), 盛英佩(Sheng Y P). 塑料科技(Plastic Science and Technology), 2014, 7: 35.
[48]  Wen X Q, Liu X H, Liu G S. IEEE T. Plasma Sci., 2010, 38(11): 3152.
[49]  Ito R, Seshimo F, Haishima Y, Hasegawa C, Isama K, Yagami T, Nakahashi K, Yamazaki H, Inoue K, Yoshimura Y. Int. J. Pharm., 2005, 303(1): 104.
[50]  da Silva F F, da S Aquino K A, Araujo E S. Polym. Degrad. Stab., 2008, 93(12): 2199.
[51]  Baccaro S, Brunella V, Cecilia A,Costa L. Nucl. Instrum. Meth. B, 2003, 208: 195.
[52]  Ito R, Seshimo F, Miura N, Kawaguchi M, Saito K, Nakazawa H. J. Pharmaceut. Biomed., 2006, 41(2): 455.
[53]  Ito R, Miura N, Ushiro M, Kawaguchi M, Nakamura H, Iguchi H, Ogino J, Oishi M, Wakui N, Iwasaki Y, Saito K, Nakazawa H. Int. J. Pharm., 2009, 376(1/2): 213.
[54]  Jayakrishnan A, Sunny M C. Polymer, 1996, 37(23): 5213.
[55]  Lakshmi S, Jayakrishnan A. Biomaterials, 2002, 23(24): 4855.
[56]  Lakshmi S, Jayakrishnan A. J. Biomed. Mater. Res. B, 2003, 65(1): 204.
[57]  Lakshmi S, Jayakrishnan A. Artif. Organs, 1998,22(3): 222.
[58]  Amberg-Schwab S, Katschorek H, Weber U, Burger A, Hansel R, Steinbrecher B, Harzer D. J. Sol-Gel Sci. Technol., 2003, 26(1/3): 699.
[59]  Messori M, Toselli M, Pilati F, Fabbri E, Fabbri P, Pasquali L, Nannarone S. Polymer, 2004, 45(3): 805.
[60]  Massard C, Bernard L, Cueff R, Raspal V, Feschet-Chassot E, Sibaud Y, Sautou V, Awitor K O. Prog. Org. Coat., 2012, 75(1/2): 116.
[61]  Bernard L, Cueff R, Massard C, Blavignac C, Awitor K O, Chopineau J, Sautou V. J. Appl. Polym. Sci., 2014, 131(8): 40145.
[62]  Meer P F, Reesink H W, Panzer S, Wong J, Ismay S, Keller A, Pink J, Buchta C, Compernolle V, Wendel S. Vox Sang., 2014, 106(2): 176.
[63]  European Chemicais Agency. Candidate List of Substances of Very High Concern for Authorisation, (2008-10-28). . http://echa.europa.eu/web/guest/candidate-list-table
[64]  Lindstrom A. Environmentally Friendly Plasticizers for PVC: Improved Material Properties and Long-term Performance Through Plasticizer Design, (2007-02-16). . http://www.diva-portal.org/smash/get/diva2: 11561/FULLTEXT01.pdf
[65]  European Chemicals Agency. Evaluation of new scientific evidence concerning DINP and DIDP in relation to entry 52 of Annex XVII to REACH Regulation (EC) No 1907/2006(final review report), (2013-08-30). . http://echa.europa.eu/documents/10162/31b4067e-de40-4044-93e8-9c9ff1960715
[66]  Content S. Plast. Eng., 2013, 69(10): 48.
[67]  Ito R, Miura N, Iguchi H, Nakamura H, Ushiro M, Wakui N, Nakahashi K, Iwasaki Y, Saito K, Suzuki T. Int. J. Pharm., 2008, 360(1): 91.
[68]  Kastner J, Cooper D G, Maric M, Dodd P, Yargeau V. Sci. Total Envir., 2012, 432: 357.
[69]  Liu Y, Zhang R, Wang X, Sun P, Chen W, Shen J, Xue G. Polymer, 2014, 55(12): 2831.
[70]  Wadey B L. J. Vinyl Additive Technol., 2003, 9(4): 172.
[71]  Demir A, Ulutan S. J. Appl. Polym. Sci., 2013, 128(3): 1948.
[72]  Barber E D, Fox J A, Giordano C J. Xenobiotica, 1994, 24(5): 441.
[73]  Tomita I, Nakamura Y, Aoki N, Inui N. Environ. Health Persp., 1982, 45: 119.
[74]  Mitchell A M, Lhuguenot J C, Bridges J W, Elcombe C R.Toxicol. Appl. Pharm., 1985, 80(1): 23.
[75]  Kambia K, Dine T, Azar R, Gressier B, Luyckx M, Brunet C. Int. J. Pharm., 2001, 229(1): 139.
[76]  International Organization for Standardization. ISO472-2013: Plastics—Vocabulary, (2013-01-30). http://www.iso.org/iso/home/store/catalogue_tc/catalogue_detail.htm?csnumber=44102
[77]  Prud'Homme R E. Polym. Eng. Sci., 1982, 22(2): 90.
[78]  Ziska J J, Barlow J W, Paul D R. Polymer, 1981, 22(7): 918.
[79]  石万聪(Shi W C), 石志博(Shi Z B), 蒋平平(Jiang P P). 增塑剂及其应用(Plasticizer and Its Application). 北京:化学工业出版社(Beijing: Chemical Industry Press), 2002. 271.
[80]  肖尧(Xiao Y), 李喜宏(Li X H), 王彪(Wang B),汤尧(Tang Y), 王成君(Wang C J). 塑料科技(Plastic Science and Technology), 2011, 39(10): 92.
[81]  Li Y, Wang C, Wang G, Qu Z. Journal of Wuhan University of Technology-Materials Science, 2008, 23(1): 100.
[82]  Chiu F C, Min K. Polym. Int., 2000, 49(2): 223.
[83]  Rusu M, Ursu M, Rusu D. J. Thermoplast. Compos., 2006, 19(2): 173.
[84]  Thomas N L. J. Appl. Polym. Sci., 2004, 94(5): 2022.
[85]  Choi J, Kwak S. Macromolecules, 2003, 36(23): 8630.
[86]  Choi J, Kwak S. Environ. Sci. Technol., 2007, 41(10): 3763.
[87]  Balakrishnan B, Kumar D S, Yoshida Y, Jayakrishnan A. Biomaterials, 2005, 26(17): 3495.
[88]  Krishnan V K, Jayakrishnan A,Francis J D. J. Mater.Sci.: Mater. Med., 1990, 1(4): 185.
[89]  Babukutty Y, Prat R, Endo K, Kogoma M, Okazaki S, Kodama M. Langmuir, 1999, 15(20): 7055.
[90]  McGinty K M, Brittain W J. Polymer, 2008, 49(20): 4350.
[91]  Breme F, Buttstaedt J, Emig G. Thin Solid Films,2000, 377: 755.
[92]  Barreto M C, Borris J, Thomas M, Hansel R, Stoll M, Klages C. Plasma Process. Polym., 2012, 9(11/12): 1208.
[93]  Bourdeaux D, Sautou-Miranda V, Bagel-Boithias S, Boyer A, Chopineau J. J. Pharmaceut. Biomed., 2004, 35(1): 57.
[94]  Bagel-Boithias S, Sautou-Miranda V, Bourdeaux D,Tramier V, Boyer A, Chopineau J. Am. J. Health-Syst. Ph., 2005, 62(2): 182.
[95]  Tullo A H. Chem. Eng. News, 2005, 83(46): 29.
[96]  Garnaik B, Sivaram S. Macromolecules, 1996, 29(1): 185.
[97]  Kovacic T, Mrklic Z. Thermochim. Acta, 2002, 381(1): 49.
[98]  甘景镐(Gan J G). 化学世界(Chemistry World), 1963, 10: 012.
[99]  Jaeger R J, Rubin R J. Science, 1970, 170(3956): 460.
[100]  Doull J, Cattley R, Elcombe C, Lake B G, Swenberg J, Wilkinson C, Williams G, van Gemert M. Regul. Toxicol. Pharm., 1999, 29(3): 327.
[101]  Foster P, Preuss R, Sharpe R, Toppari J. Int. J. Androl., 2006, 29(1): 155.
[102]  AuBuchon J P, Estep T N, Davey R J. Blood, 1988, 71(2): 448.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133