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化学进展 2011

硼基锂盐电解质在锂离子电池中的应用

, PP. 357-365

仇卫华,阎坤,连芳,乔亚非

Keywords: 锂离子电池,电解质,双草酸硼酸锂

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Abstract:

电解质材料是锂离子电池的关键材料之一,它直接影响电池的性能。新型硼酸锂盐由于种类繁多且环境友好而越来越引起人们的重视。双草酸硼酸锂(LiBOB)是一种新型的锂盐,具有很好的成膜性能和热稳定性,是一种很有潜力替代现有商品化锂盐LiPF6的物质。本文介绍了近期新型硼基锂盐的发展状况,归纳了LiBOB基电解质的研究概况,综述了影响LiBOB基电解质的因素,讨论了LiBOB与正负极材料的相容性,并对LiBOB基聚合物电解质和LiBOB塑晶电解质的应用进行了介绍。

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