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OALib Journal期刊
ISSN: 2333-9721
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银催化的有机合成反应
, PP. 1137-1147
Keywords: 银催化,杂环合成,偶联反应,不对称反应
Abstract:
银催化的化学反应是近年来有机化学领域研究的热点,发展迅速。与其他过渡金属相比,人们一直认为银(主要指一价银盐)催化活性较低,因此通常被用作辅助催化剂或者路易斯酸(Lewisacids)参与反应。直到近年来,银才被用作重要的催化剂广泛应用于各种有机反应中。银可以活化炔等基团的π体系,进而发生分子内或分子间的亲核反应;另外,银可以参与偶联反应和诱导手性中心的生成。本文从杂环合成、偶联反应以及不对称反应三个方面综述了近年来银催化化学反应的研究进展,并对各类反应的底物要求、反应条件、反应选择性、产率以及机理的研究进行了讨论和总结。
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