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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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光催化选择性合成有机物
DOI: 10.7536/PC140401, PP. 1460-1470
Keywords: 光催化,选择性,催化转化,绿色合成
Abstract:
光催化反应比传统催化反应条件温和，不但能利用太阳能作为光源，同时，也避免了一些强氧化剂、危险还原剂和有毒物质的使用，极大地满足了人们对能源和环境的要求。通过优化光催化体系可以实现对目标产物的选择性合成，从而为有机合成提供一种绿色、节能的途径。本文综述了近年来光催化选择性合成有机物的催化剂类型，影响选择性因素和提高选择性的途径，重点就光催化材料的晶型、催化剂的合成与表面修饰、溶剂种类、催化条件等因素在聚合反应、芳香族的羟基化反应、胺的氧化反应、烯烃环氧化反应、羰基反应选择性合成有机物方面作一评述，并对光催化在选择性合成有机物的研究和进展进行了展望。
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