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OALib Journal期刊
ISSN: 2333-9721
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基于配位自组装的全共轭三联吡啶-过渡金属环状超分子的构筑及其光、电化学性能*
, PP. 1763-1771
Keywords: 三联吡啶,多边形环状超分子,配位自组装,光化学性能,电化学性能
Abstract:
2，2'6，2"-三联吡啶全共轭衍生物在与过渡金属离子配位络合后形成的全共轭配合物，因具有特殊的大π-π电子结构和金属-配体相互作用,成为构筑新型功能材料的重要基元，被广泛应用于光电转换、化学/生物检测、催化有机合成等领域。本文主要介绍近年来全共轭“三联吡啶-过渡金属离子（tpy-Mt）”环状超分子配合物的合成及其在光、电化学性能方面的研究进展,并探讨了该领域存在的问题及今后的发展方向。
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