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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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N-杂环卡宾/CO2加合物的合成及其应用*
, PP. 433-439
Keywords: N-杂环卡宾,CO2,加合物,合成,催化,配位
Abstract:
强亲核性的N-杂环卡宾（N-heterocycliccarbenes,NHC）是近年来研究最为活跃的一类小分子有机催化剂。本文综述了NHC-CO2的合成方法和NHC-CO2参与的4类重要反应。探讨了NHC-CO2作为NHC转移试剂参与的配位反应；作为CO2转移试剂和催化剂调控的CO2固定和碳酸酯合成；作为羧基配体与过渡金属配位；作为潜在的NHC催化剂催化环状单体开环聚合反应等应用。最后，展望了其发展前景。
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