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巯基酯化壳聚糖的合成及对Cd2+的去除性能研究

Keywords: 甲壳质,巯基乙酸,脱乙酰,含镉废水

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Abstract:

采用化学方法,研究了以巯基甲壳质制备巯基酯化壳聚糖的最佳合成方案。研究表明,巯基甲壳质的脱乙酰条件(包括时间、温度、氢氧化钠浓度)影响其产物巯基酯化壳聚糖对重金属镉离子的吸附效果。当脱乙酰时间为2h,温度为160℃,氢氧化钠浓度为20%时,20mg的合成产物对30mLCd2+浓度为20mg/L水样的去除率最高,达到85.46%,其对镉离子的吸附量达到28.5mg/g。通过对产物进行红外分析发现,巯基甲壳质中出现脂基特征峰值,脱乙酰后脂基并没有消失,证明最后的产物为巯基酯化壳聚糖。

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