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以废渣磷石膏为原料水热法制备硫酸钙晶须

Keywords: 磷石膏,水热法,硫酸钙晶须,可溶磷,机理

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Abstract:

以磷石膏为原料,采用水热法制备硫酸钙晶须。借助X射线衍射仪(XRD)、扫描电子显微镜(SEM)及红外光谱仪(FT-IR)等仪器对产物进行表征,研究了反应温度和时间、料浆初始固液比及不同添加剂等因素对产物形貌及可溶磷含量等的影响。结果表明,最佳反应条件为:反应温度140℃,反应时间2h,料浆固液比为1∶10,最佳添加剂及剂量为丙三醇(V醇/V总液为50%)。所得产物为六方晶系的CaSO4·0.5H2O,直径1~3μm,晶须长径比为45左右,合成率约95%,产物可溶磷含量由原样的0.41%降至0.21%。

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