OALib Journal期刊
ISSN: 2333-9721
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聚苯胺的电化学现场ESR-电导同步测量
, PP. 10-16
Keywords: 导电聚合物,电子自旋共振,聚苯胺,导电机理
Abstract:
本论文工作通过设计新型的电解池,首次实现了导电聚合物的电化学现场ESR_电导同步测量.从获得的聚苯胺ESR信号及膜电阻随电极电势变化的精细图象看出,极化子晶格的形成与消亡决定了聚苯胺的导电行为.从不同电势下聚苯胺的ESR饱和行为也得到Curie自旋与Pauli自旋相互转化的新证据.
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