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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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MCFC隔膜用γ-LiAlO_2粗细匹配料制备研究
, PP. 57-64
Keywords: 氯化物法,γ-LiAlO_2,隔膜,MCFC性能
Abstract:
用高温反应法制得γ_LiAlO2粗料.另用氯化物法先制得α_LiAlO2细料,此细料在900℃焙烧几小时,它首先转化为中间过渡型(无定型),进而再转化为γ_LiAlO2超细料.其粒度<0.18μm,BET比表面积>43m2/g.用带铸法把以上γ_LiAlO2粗细匹配料制得MCFC隔膜.用此膜组装的电池性能较高,在200和300mA/cm2放电时,电池输出电压分别为0.85V和0.75V时,功率密度高达250mW/cm2等.用匹配料制得膜性能明显优于用单一粗料制得的膜.粗细料制备工艺过程和匹配是成功的.
| [1] | LaCovangeloCD ,PascoWD .Hot_roll_milledelectrolytestructuresformoltencarbonatefuelcells[J].J .Electrochem .Soc.1988,135 :2 2 1.
|
| [2] | [2 ] LinHuaxin ,etal.Studyofmoltencarbonatefuelcellperformances[J].BatteryBimonthly,1997,2 7:110 .
|
| [3] | WangLimin ,etal.Thepreparationofultra_fineγ_LiAlO2 bycitrate[J].J.oftheChineseCeramicSociety(bi monthly) ,1997,2 5 :6 18.
|
| [4] | [4 ] LiNaichao,etal.PreparationofLiAlO2 usedasmatrixmaterialsinmoltencarbonatefuelcell[J].J.ofInor ganicMaterials,1997,12 :2 11.
|
| [5] | [5 ] LinHuaxin ,YiBaolin ,LiNaichao,etal.Investigationonfineα_LiAlO2 powerformatrixmaterialinMCFCbyMeansof“Chloride”synthesis[J].J.oftheChineseCeramicSociety(bimonthly) ,1999,2 7(4) :45 9.
|
| [6] | [6 ] PeoppelmeierKR ,ChiamgCK ,KippDO .Synthesisofhigh_surface_areaα_LiAlO2 [J].Inorg .Chem .,1988,2 7:45 2 4.
|
| [7] | ArendtRH ,CurranMJ.Alternatesynthesisofelectrolytematrixformoltencarbonatefuelcells[J].J .Elec trochem .Soc .,1980 ,12 7:16 6 0 .
|
| [8] | CompiledbyFifthLab .ofShanghaiInstituteofCeramics,ChineseAcademy .MechanicsPropertyofCeramics[M ].ShanghaiPublisherofScienceandTechnologyLiteratures,1981:32 4.
|
| [9] | WangLinsen .SpecialCeramics[M].ThePublisherofChungNanIndustrialUniversity , P .49.
|
| [10] | [10 ] CompiledbyJapanChemicalSociety .TranslatedbyDongWangtangandDongShaojun .InorganicReactioninSolidState[M].Beijing :ThePublisherofScienceandTechnology ,1985 :2 2 9.
|
| [11] | MaruHG ,PaetschL ,PigeaudA .inProc.Symp .MoltenCarbonateFuelCellTechnology(SelmanJR ,ClaarTD .eds.) [C],PV84_13(TheElectrochemicalSociety ,Pennington ,NJ,1984) .
|
| [12] | [12 ] MarezioM ,RemeikaJP .High_pressuresynthesisandcrystalstructureofα_LiAlO2 [J].J.Chem .Phys.,196 6 ,44 :3143.
|
| [13] | ChangCH ,MargraveJL .High_pressure_high_temperaturesynthesis,IIIDirectsynthesisofnew_high_pres sureformsofLiAlO2 andLiCaO2 andpolymorphisminLiMO2 compounds[J].J.Am .Chem .Soc.,196 8,90(8) :2 0 2 0 .
|
| [14] | LinHuaxin ,etal.TheStudyontheperformanceMCFCmatrixpreparedbyflowcast[J].Electrochemistry(Chinese) ,1998,4:40 6 .
|
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