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电化学  2001 

制备条件对PANI/PATP/Au和TiO_2-PANI/PATP/Au膜光电化学性能的影响

, PP. 155-160

Keywords: TiO2,聚苯胺,光电化学

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Abstract:

应用电化学方法在不同条件下制备聚苯胺(PANI)膜和TiO2-PANI复合膜,并对其光电化学性能进行研究.实验表明,制备条件是影响膜光电化学性能的重要因素.对氨基硫酚(PATP)的组装有利于改善PANI膜的附着力;部分氧化态PANI膜的光电化学响应明显优于还原态和氧化态PANI膜的光电化学响应;部分氧化态PANI膜的厚度对其光电化学性能有一最佳值;热处理虽然有利于改善TiO2的光电化学性能,但温度太高,将破坏PANI膜的表面结构,对于TiO2-PANI复合膜有一最佳的热处理温度.优化制备条件大可改善TiO2-PANI复合膜和PANI膜的光电化学性能

References

[1]   WANGLi_Xiang ,WANGFo_Song .ProgressinPolyanilineAsaNovelConductingPolmer[J].ChineseJournalofAppliedChemistry ,1990 ,7(5) :1.
[2]  [2 ]  KilmartinPA ,WrightGA .Photoeffectsatpolyanilinefilmelectrode[J].Electrochim .Acta ,1996 ,4 1:16 77.
[3]   KilmartinPA ,WrightGA .Anioninsertionandexpulsioninpolyanilineelectrodesstudiedbyphotocurrenttransients[J].Electrochim .Acta ,1998,4 3:30 91.
[4]  [4 ]  StafstromS ,BredasJL ,EpsteinAJ,etal.Polaronlatticeinhighlyconductingpolyaniline:theoreticalandop ticalstudies[J].Phys .Rev .Lett,1987,59:146 4 .
[5]   McCallRP ,GrinderJM ,LengJM ,etal.Spectroscopyanddefectstatesinpolyaniline[J].Phys.Rev .B ,1990 ,4 1:52 0 2 .
[6]  [6 ]  HUANGHuai_Guo ,LUO_Jin ,ZHANGHong_Ping ,etal.ThephotoelectrochemistryofAu/PATP/PANIfilmelectodeandAu/PATP/PANI/TiO2 filmelectrode[J].Chem .J .ChineseUniversities ,2 0 0 0 ,2 1:2 83.
[7]   HUANGHuai_Guo ,LUOJin ,ZHANGHong_Ping ,etal.ThephotoelectrochemistryofTiO2 _Polyanilinecom positefilm[J].ChineseJournalofElectrochemistry ,2 0 0 1,7(1) :10 2
[8]   ZHANGHong_Ping ,LUO_Jin ,HUANGHuai_Guo ,etal.OrderedNano_structuredpolymerfilmsofPATP/PANIbyelectrochemical_assembly[J].Chem .J.ChineseUniversities,1999,2 0 :6 2 4 .
[9]   LUO_Jin ,LINZhong_Hua ,WULing_Ling ,etal.Insituelectronicspectroscopictechniquesforinterfacialelec trochemisty[J].Chem .ResearchinChineseUniv .,1996 ,12 :2 70 .
[10]  [10 ]  NuzzoRG ,AllaraDL .Adsorptionofbifunctionalorganicdisulfidesongoldsurfaces[J].J .Am .Chem .Soc.,1983,10 5:4 4 81.
[11]   WilliamAH ,CurtisS .Electrochemistryofsurface_confinedmixedmixedmonolayersof 4_aminothiophinolandthiophenolonAu[J].Langmuir ,1996 ,12 :36 88.
[12]  [12 ]  RubinsteinI ,RishponJ,SabataniE ,etal.Morphologycontrolinelectrochemicallygrownconductingpolymerfilms.I .Precoatingthemetalsubstratewithanorganicmonolayer[J].J .Am .Chem .Soc.,1990 ,112 :6 135.
[13]   SabatanlE ,RedondoA ,RishponJ ,etal.Morphologycontrolinelectrochemicallygrownconductingpolymerfilms.2 .effectsofcathodicbiasonanodicallygrownfilmsstudiedbyspectroscopicellipsonetryandquartz_crystalmicrobalance[J].J.Chem .Soc .Faraday .Trans .,1993,89(2 ) :2 87.
[14]   SabatanlE ,GafniY ,RubinsteinI .Morphologycontrolinelectrochemicallygrownconductingpolymerfilms .3.Acomparativestudyofpolysnilinefilmsonbaregoldandongoldpretreatedwithp_aminothiophenol[J].J .Phys.Chem .,1995,99:12 30 5.
[15]   DosSantosMC ,BredasJL .Nonlinearexcitationsinpernigraniline ,theoxidizedformofpolyaniline[J].Phys.Rev .Lett .,1989,6 2 (2 1) :2 4 99.
[16]  [16 ]  McCallR .P .,GinderJ.M .,LengJ .M .etal.Spectroscopyanddefectstatesinpolyaniline[J].Phys .Rev .B .,1990 ,4 1(8) :52 0 2 .
[17]   LuoJ ,HuangHG ,ZhangHP ,etal.Studiesonphotoelectrochemistryofnano_particulateTiO2 /PANI/PATPfilmonAuelectrodes[J].J.NewMAT .Electrochem .Systens,2 0 0 0 ,3:2 4 9

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