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催化学报 2010
无溶剂条件下锰(Ⅲ)-席夫碱配合物催化过氧化氢氧化醇, PP. 615-618 Keywords: alcohol,oxidation,hydrogenperoxide,Schiff-basecomplex,Mn(III)complex,ketone Abstract: ？AliphaticandaromaticalcoholsareefficientlyoxidizedtoketonesorcarboxylicacidsusingaqueoushydrogenperoxideasanoxidantinthepresenceofaMn(III)Schiff-basecomplexasacatalystundersolvent-freeconditions.Theoxidationofalcoholsoccurredat50°Ctogivethecorrespondingketonesorcarboxylicacidswithayieldhigherthan60%.
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